Citation: CHEN Jiao-jiao, CHEN Guan-yi, MA Wen-chao, MA Long-long, WANG Tie-jun, ZHANG Qi, LÜ Wei. Experimental study of aromatics production from catalytic cracking of bio-oil model compounds[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(2): 183-188. shu

Experimental study of aromatics production from catalytic cracking of bio-oil model compounds

1.
1. School of Environmental Science & Engineering, State Key Laboratory of Engines of Tianjin University, Tianjin University, Tianjin 300072, China;

Corresponding author: CHEN Guan-yi, MA Long-long,
Received Date: 16 August 2012
Available Online: 18 October 2012
Fund Project: 国家自然科学基金(51036006) (51036006) 国家高技术研究发展计划(863计划, 2012AA051801) (863计划, 2012AA051801) 中国博士后科学基金(2011M501347)。 (2011M501347)

Catalytic cracking experiments were performed for bio-oil model compounds (acetic acid, guaiacol, n-heptane and hexamethylene, etc) using HZSM-5 molecular sieve catalyst at 550℃, aiming to study the reaction mechanism and catalyst properties. The results show that the main product for catalytic cracking of n-heptane and hexamethylene is aromatics (53% and 91%, respectively in area). Catalytic cracking reaction occurs more easily for those oxygen-free model compounds. The aromatics content increase effectively (from 12% to 90% in area) with increasing addition of catalyst for acetic acid. The guaiacol structure is quite complex and the catalyst mainly removes its methoxy group. Increasing the weight of catalyst could lead to aromatics formation more easily.
- model compound,
- catalytic cracking,
- bio-oil,
- HZSM-5,
- aromatics
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