生物油模型化合物催化裂化制备芳香烃的实验研究

陈娇娇 陈冠益 马文超 马隆龙 王铁军 张琦 吕微

引用本文: 陈娇娇, 陈冠益, 马文超, 马隆龙, 王铁军, 张琦, 吕微. 生物油模型化合物催化裂化制备芳香烃的实验研究[J]. 燃料化学学报, 2013, 41(2): 183-188. shu
Citation:  CHEN Jiao-jiao, CHEN Guan-yi, MA Wen-chao, MA Long-long, WANG Tie-jun, ZHANG Qi, LÜ Wei. Experimental study of aromatics production from catalytic cracking of bio-oil model compounds[J]. Journal of Fuel Chemistry and Technology, 2013, 41(2): 183-188. shu

生物油模型化合物催化裂化制备芳香烃的实验研究

    通讯作者: 陈冠益,教授,主要从事生物能源转化技术及其利用等方面的研究,Tel:022-87402075,E-mail:chen@tju.edu.cn;马隆龙,研究员,主要从事生物液体燃料制备的研究,E-mail:mall@ms.giec.ac.cn。; 陈冠益,教授,主要从事生物能源转化技术及其利用等方面的研究,Tel:022-87402075,E-mail:chen@tju.edu.cn;马隆龙,研究员,主要从事生物液体燃料制备的研究,E-mail:mall@ms.giec.ac.cn。
  • 基金项目:

    国家自然科学基金(51036006) (51036006)

    国家高技术研究发展计划(863计划, 2012AA051801) (863计划, 2012AA051801)

    中国博士后科学基金(2011M501347)。 (2011M501347)

摘要: 通过HZSM-5分子筛催化剂对生物油典型模型化合物(乙酸、愈创木酚、正庚烷和环己烷等)在550℃进行了催化裂化反应,研究模型化合物催化裂化特性和反应机理以及催化剂性质。结果表明,正庚烷和环己烷裂化产物主要是芳香烃(53%和91%,均为积分面积分数),对于此类不含氧的模型化合物,催化裂化反应过程更容易进行;随着催化剂用量的增加,可以有效增加乙酸裂化产物中芳香烃含量(12%到90%,均为积分面积分数);愈创木酚结构比较复杂,HZSM-5催化剂主要脱除了甲氧基,催化剂用量的增加可以使芳香烃类稳定物质更容易形成。

English

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  • 收稿日期:  2012-08-16
  • 网络出版日期:  2012-10-18
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