Citation:
PENG Kang, WANG Yi-fei, JIN Wei-long, WU Chao-qi, WANG Fu-chen. Effects of calcium nitrate on pyrolysis and gasification behavior of lignite from Inner Mongolia[J]. Journal of Fuel Chemistry and Technology,
;2013, 41(2): 144-150.
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The pyrolysis of original coal(a lignite from Inner Mongolia), acid washing deashed coal and calcium nitrate loaded coal was investigated in a small fixed-bed reactor, and the gasification activity with steam for different chars was compared as well. The results show that both coal pyrolysis and gasification processes are affected by addition of calcium nitrate. Calcium nitrate can obviously promote the pyrolysis reaction and change the release regularity and cumulative quantity of main gaseous products(H2, CO2 and CO); while the alkaline-earth metal as a catalyst can reduce the gasification activation energy and promote the char gasification with steam.
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Keywords:
- calcium nitrate,
- coal pyrolysis,
- coal gasification,
- gaseous products
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[1]
[1] 杨景标, 蔡宁生. 应用TG-FTIR联用研究催化剂对煤热解的影响[J].燃料化学学报, 2006, 34(6): 650-654. (YANG Jing-biao, CAI Ning-sheng. A TG-FTIR study on catalytic pyrolysis of coal[J]. Journal of Fuel Chemistry and Technology, 2006, 34(6): 650-654.)
-
[2]
[2] 杨会民, 王美君, 张玉龙, 常丽萍. 添加物对宁夏煤热解气相产物生成的影响[J].煤炭学报, 2010, 35(8): 1364-1368. (YANG Hui-min,WANG Mei-jun,ZHANG Yu-long,CHANG Li-ping. Effects of additives on Ningxia coal pyrolysis behavior[J]. Journal of China Coal Society, 2010, 35(8): 1364-1368.)
-
[3]
[3] YASUO O, EDWARD F. Effect of ultrafine iron and mineral matter on conversion of nitrogen and carbon during pyrolysis and gasification of coal[J]. Energy Fuels, 1995, 9(1): 141-147.
-
[4]
[4] LIU Q, HU H, ZHOU Q, ZHU S, CHEN G. Effect of inorganic matter on reactivity and kinetics of coal pyrolysis[J]. Fuel, 2004, 83(6): 713-718.
-
[5]
[5] MAŠEK O, SONOYAMA N, OHTSUBO E, HOSOKAI S, LI C-Z, CHIBA C, HAYASHI J-I. Examination of catalytic roles of inherent metallic species in steam reforming of nascent volatiles from the rapid pyrolysis of a brown coal[J]. Fuel Process Technol, 2007, 88(2): 179-185.
-
[6]
[6] 管仁贵, 李 文, 李保庆. 钙基添加剂在大同煤热解中的作用[J]. 中国矿业大学学报, 2002, 31(4): 396-401. (GUAN Ren-gui, LI Wen, LI Bao-qing. Effects of Ca-based additives on pyrolysis of Datong coal[J]. Journal of China University of Mining & Technology, 2002, 31(4): 396-401.)
-
[7]
[7] QUYM D M, WU H, HAYASHI J-I, LI C-Z. Volatilisation and catalytic effects of alkali and alkaline earth metallic species during the pyrolysis and gasification of Victorian brown coal: Part IV Catalytic effects of NaCl and ion-exchangeable Na in coal on char reactivity[J]. Fuel, 2003, 82(5): 587-593.
-
[8]
[8] 许慎启, 周志杰, 代正华, 于广锁, 龚欣. 碱金属及灰分对煤焦碳微晶结构及气化反应特性的影响[J]. 高校化学工程学报, 2010, 24(1): 64-70. (XU Shen-qi, ZHOU Zhi-jie, DAI Zheng-hua, YU Guang-suo, GONG Xin.Effects of alkalimetal and ash on crystallite structure of coal char during pyrolysis and on gasification reactivity[J]. Journal of Chemical Engineering of Chinese Universities, 2010, 24(1): 64-70.)
-
[9]
[9] ATUL S, TOSHIMASA T, IKUO S. Effect of catalyst addition on gasification reactivity of HyperCoal and coal with steam at 775~700℃[J]. Fuel, 2008, 87(12): 2686-2690.
-
[10]
[10] LIN S, HARADA M, SUZUKI Y, HATANO H. Comparison of pyrolysis products between coal, coal/CaO, and coal/Ca(OH)2 materials[J]. Energy Fuels, 2003, 17(3): 602-607.
-
[11]
[11] ANTHONY H C, LEONARD F D, TREVOR W M. The effect of calcium on the rate and products of steam gasification of char from low rank coal[J]. Fuel, 1998, 77(9/10): 1017-1020.
-
[12]
[12] 熊 杰, 周志杰, 许慎启, 于广锁. 碱金属对煤热解和气化反应速率的影响[J]. 化工学报, 2011, 62(1): 192-198. (XIONG Jie, ZHOU Zhi-jie, XU Shen-qi, YU Guang-suo. Effect of alkali metal on rate of coal pyrolysis and gasification[J]. Journal of Chemical Industry and Engineering(China), 2011, 62(1): 192-198.)
-
[13]
[13] 谢克昌. 煤的结构与反应性[M]. 北京: 科学出版社, 2002. (XIE Ke-chang. Coal structure and its reactivity[M]. Beijing: Science Press, 2002.)
-
[14]
[14] 杨景标, 蔡宁生, 张彦文. 催化剂添加量对褐煤焦水蒸气气化反应性的影响[J]. 燃料化学学报, 2008,36(1): 15-22. (YANG Jing-biao, CAI Ning-sheng, ZHANG Yan-wen. Effect of catalyst loadings on the gasification reactivity of a lignite char with steam[J]. Journal of Fuel Chemistry and Technology, 2008,36(1): 15-22.)
-
[15]
[15] LI C-Z, SATHE C, KERSHAW J R, PANG Y. Fates and roles of alkali and alkaline earth metals during the pyrolysis of a Victorian brown coal[J]. Fuel, 2000, 79(3/4): 427-438.
-
[16]
[16] LI X, LI C-Z. Volatilisation and catalytic effects of alkali and alkaline earth metallic species during the pyrolysis and gasification of Victorian brown coal: Part VIII Catalysis and changes in char structure during gasification in steam[J]. Fuel, 2006, 85(10/11): 1518-1525.
-
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