Citation: Chun Yan HAO, Zi Yang LIU, Xing Hua GUO, Shu Ying LIU. Formation of Heterocyclic C₆₀ Derivative by Gas-Phase Ion/molecule Reaction[J]. Chinese Chemical Letters, ;1997, 8(5): 375-376. shu

Formation of Heterocyclic C₆₀ Derivative by Gas-Phase Ion/molecule Reaction

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 21 October 1996

Ion/molecule reactions of C₆₀ with vinyl acetate under chemical ionization conditions have been studied here.Compared with C₂H₃O^- from acetone. C₂H₃O^- from vinyl acetate undergoes the reactions more easily,a new heterocycle between C₆₀ and the studied ion is formed.The generation of two σ-bonds and little angle tensile force of pentatomic ring make it more stable.
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