Citation: Yan-Fang Geng, Shi-Li Wu, Jing Xu, Hong-Liang Dai, Xiao-Kang Li, Ke Deng, Qing-Dao Zeng. Formation of heterocaryotic and homonuclear bridged-dimeric complexes on surface[J]. Chinese Chemical Letters, ;2016, 27(4): 602-606. shu

Formation of heterocaryotic and homonuclear bridged-dimeric complexes on surface

a CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology(NCNST), Beijing 100190, China;
b Key Laboratory of Organo-pharmaceutical Chemistry, Gannan Normal University, Ganzhou 341000, China

Received Date: 4 December 2015
Revised Date: 31 December 2015

Fund Project: Thisworkwas supported by theNational Basic Research Program of China (No. 2013CB934200), National Basic Research Program of China (No. 2012CB933001), The Chinese Academy of Sciences (No. YZ201318) and the National Natural Science Foundation of China (Nos. 21472029, 51173031, 91127043, 51203030, 51463002).

The formation of coordinated dimeric complexes bridged by axial ligands on surface is observed with the help of a 1, 3, 5-tris(10-carboxydecyloxy)benzene (TCDB) template through scanning tunneling microscopy (STM). STM images of molecular adlayers of zinc tetraphenylporphyrin (ZnTPP), zinc phthalocyanine (ZnPc), and their mixture are reported. ZnTPP and ZnPc can spontaneously form highly an ordered structure with a 1:1 molar ratio, which is different from that of individual ZnPc. The coordinated bimolecular complexes bridged with axial ligands, simply as ZnPc-DPP-ZnTPP and ZnPc-DPE-ZnPc, are presented and the corresponding surface structures are compared. ZnPc and ZnTPP can be connected by an axial ligand DPP and formed assembled structures out of surface. Two types of arrays with entirely new structure are obtained for the ZnPc-DPE-ZnPc complex. These bridged hybrid complexes provide an example of design of self-organized crystals on the basis of coordination through non-covalent interactions.
- Coordinated dimeric complexes,
- Zinc tetraphenylporphyrin (ZnTPP),
- Zinc phthalocyanine (ZnPc),
- Scanning tunneling microscopy (STM),
- Axial ligands
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