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Citation: Liu Yifan, Chen Dianbao, Dong Jiyuan, Tang Xueming. Products of Substituftion Reaction Between MoCl₅ and C₇H₁₅COOH and Their Enects on Butadiene Polymerization[J]. Chinese Journal of Applied Chemistry, ;1994, 11(1): 24-27. shu

Products of Substituftion Reaction Between MoCl₅ and C₇H₁₅COOH and Their Enects on Butadiene Polymerization

1.
Department of Chemisry Engineering, Qingdao Institute of Chemical Technology, Qingdao 266042

Received Date: 22 December 1992
Available Online: 8 September 1993
Fund Project:

The effects of the conditioiis of reaction between MoCl₅ and,n-C₇H₁₅COOH on thenumber of chlorine atorn in MoCl₅ substituted by functional group C₇H₁₅ COO have beenstudied. The UV-Vis spectra of the exchange products MoCl₅ m(n-C₇H₁₅COO)m were dis-cussed and assigned. The catalytic activity of the molybdenum catalyst system containing MoCl₅ m(n-C₇H₁₅COO)m for butadiene polymerization was found to be decreased rapidly withincreasing the number of substituted chlorine atoms in MoCl₅.
- molybdenum pentachoride,
- octanoic acid,
- Ziegler-Natta catalyst,
- butadiene poly merization
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Products of Substituftion Reaction Between MoCl₅ and C₇H₁₅COOH and Their Enects on Butadiene Polymerization