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Citation: Cheng Lin, Jian Xigao, Chen Shoushan, Qian Yanlong. Syntheses and Spectra of Bulkier Substituted Titanocene Zirconocene Dichlorides[J]. Chinese Journal of Applied Chemistry, ;1997, 14(2): 50-52. shu

Syntheses and Spectra of Bulkier Substituted Titanocene Zirconocene Dichlorides

1.
1. Department of Polymer Science and Materials, College of Chemical Engieering, Dalian University of Science and Technology, Dalian 116012;
2.
Elemento Organic Chemistry Institute, Nankai University, Tianjin;
3.
3. Department of Chemistry, East China University of Science and Technology, Shanghai

Received Date: 26 June 1996
Available Online: 22 October 1996
Fund Project:

Seven bulkier substitute titanocene and zirconocene dichlorides have been synthesized by addition reaction of 6,6-dialkylfulvenes with 1-lithiocyclohexene followed by treatment of the obtained bulkier substituted metallocene with MCl₄(M=Ti, Zr). Their ¹H NMR, EIMS and IR spectra have been discussed.
- addition reaction,
- substituted cyclopentadienyl metal compound,
- spectra
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