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Citation: Yuan Jinying, Pan Caiyuan, Bai Ruke. Synthesis, Cationic Polymerization and Curing Reaction with Epoxy Resin of a New Spiro Ortho Carbonate[J]. Chinese Journal of Applied Chemistry, ;1997, 14(1): 25-28. shu

Synthesis, Cationic Polymerization and Curing Reaction with Epoxy Resin of a New Spiro Ortho Carbonate

1.
1. College of Chemical Engineering, University of Technology of Hefei, Hefei 230009;
2.
2. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei

Received Date: 23 April 1996
Available Online: 17 September 1996
Fund Project:

A new spiro ortho carbonate 3,9-di(p-methoxybenzyl)-1,5,7,11-tetroxaspiro[5,5] undecane(1) was prepared. Its cationic polymerization was carried out. The ¹H NMR, ¹³C NMR and IR data as well as elemental analysis of the obtained polymers indicated that it underwent double ring-opening polymerization. The polymerization mechanism was discussed. DSC and IR were used to trace the curing process of epoxy resin with or without this monomer. The effects of curing agent and curing condition on curing reaction were investigated.
- spiro ortho carbonate,
- cationic polymerization,
- double ring-opening polymerization,
- epoxy resin,
- curing reaction
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