Citation: Zhang Panpan, Luo Xuegang, Wang Xin, Chen Ye. Direct Conversion of Syngas to Ethylene over Fe-Mo/Cordierite Catalysts[J]. Chemistry, ;2016, 79(12): 1145-1149. shu

Direct Conversion of Syngas to Ethylene over Fe-Mo/Cordierite Catalysts

1.
School of Material Science and Engineering, Southwest University of Science and Technology;Engineering Research Center of Biomass Materials, Ministry of Education, Southwest University of Science and Technology, Mianyang 621010

Corresponding author: Luo Xuegang,
Received Date: 24 May 2016
Available Online: 14 September 2016
Fund Project:

Cordierite loaded Fe-Mo catalyst was prepared by impregnation method. The structure and morphology of the catalyst were characterized by SEM, FT-IR, XRD, EDX and XPS methods. It was found that the catalyst calcined at 450℃ under argon atmosphere has superior performance in the catalytic synthesis of ethylene. In addition, effects of the reaction temperature, air velocity and H₂/CO molar ratio on catalytic performance were also discussed. Under the reaction conditions of H₂/CO=2, WHSV=2.0 L/g cat·h, and 450℃, the selectivity of ethylene and carbon monoxide conversion rate were 46.3% and 63.5%, respectively. The Fe-Mo-cat has high ethylene efficiency for syngas conversion, and this study may provide a new reference for industrial production of ethylene.
- Cordierite,
- Catalyst,
- Syngas,
- Carbon monoxide,
- Ethylene,
- Selectivity
1. [1]
  [1] J Z Lu, L J Yang, B L Xu et al. ACS Catal., 2014, 4: 613~621.
2. [2]
  [2] N Lohitharn, J G Goodwin, E Lotero. J. Catal., 2008, 255: 104~113.
3. [3]
  [3] C F Wang, X L Pan, X H Bao. Chin. Sci. Bull., 2010, 55: 1117~1119.
4. [4]
  [4] 吴宝山, 白亮, 张志新等. 催化学报. 2005, 26: 371~376.
5. [5]
  [5] Y Liu, J F Chen, Y Zhang. React. Kinet. Mech. Cat., 2015, 114: 433~449.
6. [6]
  [6] J B Li, H F Ma, H T Zhang et al. React. Kinet. Mech. Cat., 2014, 112: 409~423.
7. [7]
  [7] A A Mirzaeia, R Habibpour, E Kashi. Appl. Catal. A-Gen. 2005, 296: 222~231.
8. [8]
  [8] 位键, 马现刚, 方传艳等. 燃料化学学报, 2014, 42: 827~832.
9. [9]
  [9] S A Al-Sayari. Ceram. Int., 2014, 40: 723~728.
10. [10]
  [10] W Ma, E L Kugler, J Wright et al. Energy Fuels, 2006, 20: 2299~2307.
11. [11]
  [11] S Qin, C Zhang, J Xu et al. J. Mol. Catal. A, 2009, 304: 128~134.
12. [12]
  [12] 秦绍东, 张成华, 许健等. 燃料化学学报, 2012, 40: 221~228.
13. [13]
  [13] O V Klimov, A V Pashigreva, G A Bukhtiyarova et al. Catal. Today, 2010, 150: 196~206.
14. [14]
  [14] M Lu, P M Lv, Z H Yuan et al. Renew. Energy, 2013, 60: 522~528.
15. [15]
  [15] 华金铭, 郑起, 魏克镁等. 分子催化, 2006, 20: 550~555.
16. [16]
  [16] 刘艳春, 王兆春, 曾令可等. 分析测试学报, 2014, 33: 1044~1049.
17. [17]
  [17] 王丽间, 李欣, 夏启斌等. 功能材料, 2012, 43: 835~838.
18. [18]
  [18] M D Shroff, D S Kalallad, K E Coulter et al. J. Catal., 1995, 156: 185~207.
19. [19]
  [19] D S Kalakkad, M D Shroff, K Steve et al. Appl. Catal. A, 1995, 133: 335~350.
20. [20]
  [20] 赵金双, 娄晓荣, 王婧等. 煤炭转化, 2014, 37: 92~96.
21. [21]
  [21] 娄晓荣, 李伟, 李哲. 工业催化, 2012, 20: 29~34.
22. [22]
  [22] Y Xiong, J Ye, X Gu et al. J. Phys. Chem. C, 2007, 111: 6998~7003.
23. [23]
  [23] 王洪, 郝庆兰, 相宏伟等. 燃料化学学报, 2005, 33: 89~94.
24. [24]
  [24] E T Liakakou, E Heracleous, K S Triantafyllidis et al. J. Appl. Catal. B, 2015, 165: 296~305.
25. [25]
  [25] 李剑锋, 陶跃武, 周晓峰等. 化学反应工程与工艺, 2010, 26: 486~493.
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
3. [3]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
4. [4]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
5. [5]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043
6. [6]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
7. [7]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
8. [8]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
9. [9]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
10. [10]
  Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015
11. [11]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
12. [12]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
13. [13]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
14. [14]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
15. [15]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
16. [16]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
17. [17]
  Zhi Chai , Huashan Huang , Xukai Shi , Yujing Lan , Zhentao Yuan , Hong Yan . Wittig反应的立体选择性. University Chemistry, 2025, 40(8): 192-201. doi: 10.12461/PKU.DXHX202410046
18. [18]
  Ruilan Fan , Xiaoling Huang . 磷源的选择及三种含磷阻燃剂的合成与阻燃性. University Chemistry, 2025, 40(8): 181-191. doi: 10.12461/PKU.DXHX202410025
19. [19]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
20. [20]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(273)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142