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Citation: ZHENG Gen-Wen, WEN Sheng, LIU Yan-Li, XIE Xiao-Lin. Preparation of Polyacrylate-Vinylidene Chloride/Nanomontmorillonite Composite Emulsion[J]. Chinese Journal of Applied Chemistry, ;2009, 26(8): 944-947. shu

Preparation of Polyacrylate-Vinylidene Chloride/Nanomontmorillonite Composite Emulsion

1.
a School of Chemistry and Materials Science, Xiaogan College, Xiaogan 432000;
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b School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan

Corresponding author: ZHENG Gen-Wen,
Received Date: 18 July 2008
Available Online: 20 January 2009
Fund Project: 湖北省教育厅科学技术研究资助项目(2003j002) (2003j002)

Polyacrylate-vinylidene chloride/montmorillonite copolymer composite emulsion was prepared by seed emulsion polymerization with vinylidene chloride and montmorillonite as the modifiers.The influences of the montmorillonite content on the composite emulsion particle diameter,tensile strength,elongation at break and thermal stability were studied.The results show that the average particle size of PEA-VDC/MMT copo-lymer latex particles increased from 141 nm to 243 nm when the montomorillonite content was increased from 1% to 5%.The largest tensile strength and the elongation at break of the composite membrane were respe-ctively 3.23 MPa and 1 330% when the montomorillonite content was 2%.When the montomorillonite content was increased from 1% to 4%,the char yield and thermal decomposition temperature of PEA-VDC were enhanced,and the copolymer's thermal stability was strengthened,too.
- polyacrylate,
- vinylidene chloride,
- montmorillonite,
- composite emulsion
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