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Citation: Hua Ruimao, Zhang Suizhi, Yang Zhenyun, Song Yongrui. A CHIRAL 1,6-DIPHOSPHINE AND ITS Rh(Ⅰ)-COMPLEX IN ASYMMETRIC HYDROGENATION[J]. Chinese Journal of Applied Chemistry, ;1990, 7(3): 79-81. shu

A CHIRAL 1,6-DIPHOSPHINE AND ITS Rh(Ⅰ)-COMPLEX IN ASYMMETRIC HYDROGENATION

1.
Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116023

Received Date: 11 July 1989
Available Online: 30 October 1989
Fund Project:

A chiral bidentate phosphine, 2, 3-isopropyldene-1, 4-bis((diphenylphosphino) amino) bu-tane derived from L-(+)-tartaric acid has been obtained. The rhodium (Ⅰ)-complex of this ligand with (Rh(COD) ClO₄) in the asymmetric hydrogenation of three derivatives of α-aceta-midoacrylic acid gives 10.4-25.6% optical yield.
- diphosphine,
- asymmetric synthesis,
- catalyst,
- hydrogenation,
- rhodium complex
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