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Citation: Sun Tao, Yang Jihua, Pang Shufen, Ouyang Jun. POLYMERIZATION KINETICS OF BUTADIENE WITH NdCl₃·2Phen-HAI(i-Bu)₂ SYSTEM[J]. Chinese Journal of Applied Chemistry, ;1990, 7(1): 80-82. shu

POLYMERIZATION KINETICS OF BUTADIENE WITH NdCl₃·2Phen-HAI(i-Bu)₂ SYSTEM

1.
Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received Date: 14 March 1989
Available Online: 20 June 1989
Fund Project:

The kinetics of butadiene polymerization with NdCl₃·2Phen-HAl(i-Bu)₂ system (Phen=1, 10-phenanthroline) has been studied. The results show that the rate of polymerization is first order to both concentrations of monomer and neodymium complex, but 1/3 order with respect to the concentration of HAl(i-Bu)₂.The number of active center and the apparent activation energy of butadiene polymerization with this system were derermined.
- rare earth catalyst,
- butadiene,
- polymerization kinetics
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POLYMERIZATION KINETICS OF BUTADIENE WITH NdCl3·2Phen-HAI(i-Bu)2 SYSTEM

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POLYMERIZATION KINETICS OF BUTADIENE WITH NdCl₃·2Phen-HAI(i-Bu)₂ SYSTEM