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Citation:
Gong Yuqiu, Zhang Peizhi. SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF GOLD(Ⅲ) AND PLATINUM(Ⅳ) WITH SOME CROWN ETHERS[J]. Chinese Journal of Applied Chemistry,
;1989, 6(5): 31-34.
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Five solid complexes of gold (Ⅲ) or platinum (Ⅳ) with crown ethers have been prepared firstly. These complexes have been characterized by elemental analysis, IR and UV spectra,molar conductances and 1H NMR measurements. The complexes were found to have following constitution: [K(B15C5)2]AuCl4, [Na(B15C5)2]PtCl6, (K18C6)]AuCl4, [K(DB15C5)]AuCl4 and [NH4(DB24C8)]AuCl4, where B=benzo, DB=dibenzo.
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Keywords:
- Gold,
- Platinum,
- Crown ether complex
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