引用本文:
顾可权, 邹新琢. 光学活性甲苄菊酯的合成及其结构与活性关系的研究[J]. 应用化学,
1989, 6(4): 22-25.
Citation: Gu Kequan, Zou Xinzhou. OPTICALLY ACTIVE METHOXYTHRIN: SYNTHESIS AND THE STRUCTURE-ACTIVITY RELATION[J]. Chinese Journal of Applied Chemistry, 1989, 6(4): 22-25.
Citation: Gu Kequan, Zou Xinzhou. OPTICALLY ACTIVE METHOXYTHRIN: SYNTHESIS AND THE STRUCTURE-ACTIVITY RELATION[J]. Chinese Journal of Applied Chemistry, 1989, 6(4): 22-25.
光学活性甲苄菊酯的合成及其结构与活性关系的研究
English
OPTICALLY ACTIVE METHOXYTHRIN: SYNTHESIS AND THE STRUCTURE-ACTIVITY RELATION
Abstract:
The Goffinet's method for resolution of (±)-trans-chrysanthemic acid and the Campbell's method for resolution of (±)-cis-chrysanthemic acid have been improved. The(+)-cis acid and the (-)-cis acid were resolved only by using quinine alone. Four esters were obtained by esterifacation.The results showed: (1)The biological activity of Methoxythrin is in relation of the configuration of chrysanthemic acid and the ester of (-)-(1R,3R)-trans acid showed the highest activity. (2)The biological activity of the compounds varies from insect to insect tested.
-
Key words:
- Methoxythrin
- / Optical activity
- / Structure-activity relation
- / Pesticide
-
-
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 697
- HTML全文浏览量: 55
下载:
