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Citation: Ma Jingjing, Pan Hongbin, Huang Baotong. PREPARATION OF NORBORNENE GROUP-CAPPED POLYSTYRENE MACROMER[J]. Chinese Journal of Applied Chemistry, ;1986, 3(1): 60-62. shu

PREPARATION OF NORBORNENE GROUP-CAPPED POLYSTYRENE MACROMER

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 29 April 1985
Available Online: 20 August 1985

Polystyrene macromer with a norbornene end group (PS-NB) was prepared by coupling polystyrene anion (PS^-) with 5-bromomethylnorbornene (BrMNB) in a mixed solvent of cyclohexane and tetrahydrofuran (THF).Molecular structure of the macromer was characterized by ¹H NMR,IR, and GPC methods. Investigation on the coupling reaction parameters showed that presence of polar solvent THF greatly improved coupling efficiency. Without additional separation procedure, pure PS-NB was able to be synthesized when volume fraction of THF was up to 10% and [BrMNB]/[FS^-] ratio up to 4.
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