Citation: Zhang Quanzheng, Cheng Yi, Cheng Xuan, Lu Hongdian, Jiang Rui, He Longzhong, Wang xinghan. Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl₆][J]. Chemistry, ;2016, 79(6): 558-561. shu

Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl₆]

1.
1. Department of Chemistry & Materials Engineering, Hefei University, Hefei 230601;
2.
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Received Date: 26 November 2015
Available Online: 23 December 2015
Fund Project:

The supermolecular compound[PyBImH₂]·[SnCl₆] (PyBIm=2-(pyrid-4-yl)benzimidazole) had been synthesized and characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The compound crystallizes in orthorhombic P_bcn space group with the crystal cell parameters:a=7.1468(3) Å, b=15.0493(6) Å, c=16.1195(8) Å, V=1733.72(13) Å³, Z=4, D_c=2.025 g/cm³, M_r=528.63, μ(MoKα)=2.395mm^-1, F(000)=1024. The final R₁=0.0264 and wR₂=0.0665. Sn⁴⁺ is coordinated by six chloride ions in an octahedron geometry.[SnCl₆]^2- anions and[PyBImH₂]²⁺ cations are linked together via hydrogen bonds and π-π stacking interactions, forming a three-dimensional supermolecular framework.
- 2-(Pyrid-4-yl)benzimidazole,
- Supermolecule,
- Hydrothermal synthesis,
- Crystal structure
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl6]

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl₆]