Citation: Zha Xianyu, Zhang Dandan, Gao Baojiao. Syntheses of Functional Polysulfones with Bonding Salicylaldehyde-Type Bidentate Schiff Base Ligand on Side Chain and Luminescence Properties of Their Rare Earth Complexes[J]. Chemistry, ;2016, 79(1): 48-55,42. shu

Syntheses of Functional Polysulfones with Bonding Salicylaldehyde-Type Bidentate Schiff Base Ligand on Side Chain and Luminescence Properties of Their Rare Earth Complexes

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051

Corresponding author: Gao Baojiao,
Received Date: 13 May 2015
Available Online: 1 July 2015
Fund Project:

Two bidentate Schiff base ligand-functionalized PSFs, PSF-SAN and PSF-SCA were synthesized by the substitution reaction under optimal conditions, i.e. in N,N-dimethylacetamide at 80℃ from chloromethylated polysulfone (CMPSF) as starting material and the Schiff base reaction in turn. The chemical structures of products were characterized by FT IR and ¹H NMR techniques. Their binary polymer-rare earth (Tb(Ⅲ) ion and Eu(Ⅲ)) ion complexes were prepared, and their photoluminescence properties were preliminarily explored. The PSF-SAN produces strong sensitization action towards Eu(Ⅲ) ion, and the complex PSF-(SAN)₃-Eu(Ⅲ) emits red fluorescence. While the PSF-SCA produce sensitization action towards Tb(Ⅲ) ion, and the complex PSF-(SCN)₃-Tb(Ⅲ) emits green fluorescence.
- Polysulfone,
- Polymer-rare earth complex,
- 4-Hydroxysalicylaldehyde,
- Bidentate Schiff base ligand,
- Sensitization
1. [1]
  [1] C H Yan, H H Hu, C J Xu et al. J. Photochem. Photobio. A:Chem., 2009, 204:19~24.
2. [2]
  [2] T H Liu, G J Duan, Y P Zhang et al. Spectrochim. Acta Part A, 2009, 74:843~848.
3. [3]
  [3] X M Shi, R R Tang, G L Gu et al. Spectrochim. Acta Part A, 2009, 72:198~203.
4. [4]
  [4] Z A Taha, A M Ajlouni, K A Al-Hassan et al. Spectrochim. Acta Part A, 2011, 81:317~323.
5. [5]
  [5] S Setua, D Menon, A Asok et al. Biomaterials, 2010, 31:714~729.
6. [6]
  [6] D G Li, J Zhu, Z P Cheng et al. React. Funct. Polym., 2009, 69:240~245.
7. [7]
  [7] X Y Liu, Y L Hu, B Y Wang. Synth. Met., 2009, 159:1557~1562.
8. [8]
  [8] D Liu, Z G Wang. Polymer, 2008, 49:4960~4967.
9. [9]
  [9] J Xu, X H Huang, N L Zhou et al. Mater. Lett., 2004, 58:1938~1942.
10. [10]
  [10] R Shunmugam, G N Tew. Polym. Adv.Technol., 2007, 18:940~945.
11. [11]
  [11] Q L Suo, F Lu, J W Shi et al. J. Rare Earths, 2009, 27:28~32.
12. [12]
  [12] D Liu, Z G Wang, H Yu et al. Eur. Polym. J., 2009, 45:2260~2268.
13. [13]
  [13] H L Tang, Z Ma, J Yang et al. Mater. Lett., 2011, 65:3450~3453.
14. [14]
  [14] C H Yan, C J Yu, H H Hu et al. J. Rare Earths, 2009, 27:761~766.
15. [15]
  [15] B J Gao, W Zhang, Z G Zhang et al. J. Lumines., 2012, 132:2005~2011.
16. [16]
  [16] B J Gao, L Fang, J Y Men. Polymer, 2012, 53:4709~4717.
17. [17]
  [17] B J Gao, L Fang, R X Zhang et al. Synth. Met., 2012, 162:503~510.
18. [18]
  [18] B J Gao, Z W Qiao, T Chen. Mater. Chem. Phys., 2014, 143:1119~1130.
19. [19]
  [19] 陈萍虹, 高保娇, 徐迪. 化学通报, 2015, 78:558~565.
20. [20]
  [20] 杜瑞奎, 高保娇, 李延斌等. 高分子学报, 2010, 7:121~128.
21. [21]
  [21] 申艳玲, 杨云峰, 高保娇等. 高分子学报, 2007, 6:559~565.
22. [22]
  [22] Z A Taha, A M Ajlouni, K A Al-Hassan. Spectrochim. Acta Part A, 2011, 81:317~323.
23. [23]
  [23] N K Al-Rasbi, H Adams, F O Suliman. Dyes Pigments, 2014, 104:83~88.
24. [24]
  [24] B Yan, W J Wang, Y S Song. Spectrochim. Acta Part A, 2007, 66:1115~1121.
25. [25]
  [25] J Pei, X T Geng, J B Yan et al. J. Alloys Compd., 2006, 426:363~367.
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沈阳化工大学材料科学与工程学院沈阳 110142