Citation: Chen Aibing, Han Shaochang, Yu Yifeng, Sun Zhongqiang, Zhang Jian, Wang Lei. Ionothermal Synthesis of AlPO₄-42 Molecular Sieves Rapidly at High Temperature[J]. Chemistry, ;2016, 79(3): 264-267,242. shu

Ionothermal Synthesis of AlPO₄-42 Molecular Sieves Rapidly at High Temperature

1.
1. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018;
2.
2. Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201

Corresponding author: Wang Lei,
Received Date: 18 May 2015
Available Online: 30 September 2015
Fund Project:

In this work, AlPO₄-42 molecular sieves was rapidly synthesized by ionothermal synthesis with phosphoric acid as phosphorus sources and isopropanol aluminum as aluminum sources in ionic liquid [BMIM]Br at 280℃, and some other type aluminophosphate molecular sieves were synthesized by this way. XRD, SEM, BET and solid-state mas NMR were used to investigate the influence of the ratio of materials, template agent and different crystallization time on synthesis. The specific surface area, size of the entrance and filler in the pore for as-prepared AlPO₄-42 molecular sieves were characterized as well. The results indicated that the structure of AlPO₄-42 molecular sieves has been already formed after 4 min. The synthesized AlPO₄-42 molecular sieves had a tetrakaidecahedron morphology, which is obviously different with the AlPO₄-42 molecular sieves of cube morphology obtained by conventional approach, and the specific surface area and pore volume of AlPO₄-42 molecular sieves were changed too. In the process of synthesis AlPO₄-42 molecular sieves, the coordinated action of ionic liquid and template led to form the products.
- Ionothermal,
- Rapid synthesis,
- AlPO₄-42 molecular sieves
1. [1]
  [1] M E Davis. Nature, 2002, 417(6891):813~821.
2. [2]
  [2] Sujandi, S E Park, D S Han et al. Chem. Commun., 2006, (39):4131~4133.
3. [3]
  [3] J Yu, R Xu. Chem. Soc. Rev., 2006, 35(7):593~604.
4. [4]
  [4] R Murugavel, A Choudhury, M G Walawalkar et al. Chem. Rev., 2008, 108:3549~3655.
5. [5]
  [5] C S Cundy, P A Cox. Chem. Rev., 2003, 103:663~701.
6. [6]
  [6] C S Cundy, P A Cox. Micropor. Mesopor. Mater., 2005, 82(1-2):1~78
7. [7]
  [7] R E Morris, S J Weigel. Chem. Soc. Rev., 1997, 26:309~317.
8. [8]
  [8] E R Cooper, C D Andrews, P S Wheatley et al. Nature, 2004, 430:1012~1016.
9. [9]
  [9] E R Parnham, R E Morris. Acc. Chem. Res., 2007, 40(10):1005~1013.
10. [10]
  [10] R E Morri. Chem. Commun., 2009,(21):2990~2998.
11. [11]
  [11] L Wang, Y P Xu, B C Wang et al. Chem. Eur. J., 2008, 14(34):10551~10555.
12. [12]
  [12] Y Wei, Z J Tian, H Gies et al. Angew. Chem., 2010, 122:1~5.
13. [13]
  [13] L Liu, J F Yang, J P Li et al. Angew. Chem. Int. Ed., 2011, 50:8139~8142.
14. [14]
  [14] D S Wragg, G M Fullerton, P J Byrne et al. Dalton Transac., 2011, 40(18):4926~4932.
15. [15]
  [15] X J Meng, F S Xiao. Chem. Rev., 2014, 114(2):1524~1543.
16. [16]
  [16] T Welton. Chem. Rev., 1999, 99(8):2071~2083.
17. [17]
  [17] M J Earle, J Esperanca, M A Gilea et al. Nature, 2006, 439:831~834.
18. [18]
  [18] R S Xu, W P Zhang, J Xu et al. J. Phys. Chem. C, 2013, 117:5848~5854.
19. [19]
  [19] R J Francis, D J O'Hare. Chem. Soc., Dalton, Transac., 1998, 19:3133~3148.
20. [20]
  [20] A Kuperman, S Nadimi, S Oliver et al. Nature, 1993, 365, 239~242.
21. [21]
  [21] R Morris, S James. Angew. Chem. Int. Ed., 2013, 52, 2163~2165.
22. [22]
  [22] Y P Xu, Z J Tian, L Wang et al. Angew. Chem. Int. Ed., 2006, 45:3965~3970.
23. [23]
  [23] X H Zhao, H Wang, C X Kang et al. Micropor. Mesopor. Mater., 2012, 151:501~505.
24. [24]
  [24] R Y Pei, Z J Tian, Y Wei et al. Mater. Lett., 2010, 64:2118~2121.
25. [25]
  [25] Y Zhu, W Wang, R Qi et al. Angew. Chem., 2004, 116(11):1434~1438.
26. [26]
  [26] E J Fayad, N Bats, C E A Kirschhock et al. Angew. Chem. Int.Ed., 2010, 49:4585~4588.
27. [27]
  [27] E Jahn, D Müller, W Wieker et al. Zeolites,1989, 9:177~181.
28. [28]
  [28] A Corma, F Rey, J Rius et al. Nature, 2004, 431:287~290.
29. [29]
  [29] L Gómez-Hortigüela, F Lopez-Arbeloa, F Cora et al. J. Am. Chem. Soc., 2008, 130(40):13274~13284.
30. [30]
  [30] Y Nakagawa, S I Zones. in:M L Occelli, H E Robson ed. Synthesis of Microporous Materials. Vol.1-Molecular Sieves. New York:Van Nostrand Reinhold, 1992:222~239.
31. [31]
  [31] R Y Pei, Y Wei, K D Li et al. Dalton Transac., 2010, 39:1441~1443.
32. [32]
  [32] R S Xu, X C Shi, W P Zhang et al. Phys. Chem. Chem. Phys., 2010, 12:2443~2449.
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
3. [3]
  Yi RU , Tao MENG , Zhaoteng XUE , Dongsen MAO . Synergistic catalysis of Al distribution and pore structure in ZSM-5 zeolite for bioethanol-to-propylene. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 247-262. doi: 10.11862/CJIC.20250255
4. [4]
  Min Hu , Yinghuan Li , Yanhong Bai , Yanping Ren , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Faqiong Zhao , Wenwei Zhang , Mei Shi , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on the Method of Hydrothermal-Solventthermal Synthesis and Their Operation Standards. University Chemistry, 2026, 41(3): 208-215. doi: 10.12461/PKU.DXHX202507034
5. [5]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
6. [6]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
7. [7]
  Jingjie Tang , Luying Xie , Jiayu Liu , Shangyu Shi , Xinyu Sun , Jiayang Lin , Qikun Yang , Chuan'ang Yu , Zecheng Wang , Yingying Wang , Zengyang Xie . Efficient Rapid Synthesis and Antibacterial Activities of Tosylhydrazones: A Recommended Innovative Chemistry Experiment for Undergraduate Medical University. University Chemistry, 2024, 39(3): 316-326. doi: 10.3866/PKU.DXHX202309091
8. [8]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
9. [9]
  Mengxiu Li , Jiahui Mao , Jiangfeng Ni , Liang Li . Three birds with one stone: modification of Li₅FeO₄ with thermal induction of Lewis acid. Acta Physico-Chimica Sinica, 2026, 42(4): 100189-0. doi: 10.1016/j.actphy.2025.100189
10. [10]
  Yong Shu , Xing Chen , Sai Duan , Rongzhen Liao . How to Determine the Equilibrium Bond Distance of Homonuclear Diatomic Molecules: A Case Study of H₂. University Chemistry, 2024, 39(7): 386-393. doi: 10.3866/PKU.DXHX202310102
11. [11]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
12. [12]
  Qiaorong RU . Synthesis and characterization of tripyridine functionalized polyionic liquid luminescent materials. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 111-119. doi: 10.11862/CJIC.20250121
13. [13]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
14. [14]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
15. [15]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-0. doi: 10.3866/PKU.WHXB202406012
16. [16]
  Huiying ZHANG , Ping LI , Weixia DONG , Zhiwen HU , Qifu BAO , Qizheng DONG , Mingmin BAI , Wenqi LI . Photocatalytic performance of spheroidal nano Bi₄Ti₃O₁₂ prepared by surfactant-assisted hydrothermal reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 551-561. doi: 10.11862/CJIC.20250269
17. [17]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
18. [18]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
19. [19]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
20. [20]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 100026-0. doi: 10.3866/PKU.WHXB202405002

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(712)
HTML views(80)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ionothermal Synthesis of AlPO4-42 Molecular Sieves Rapidly at High Temperature

Metrics

通讯作者: 陈斌, bchen63@163.com

Ionothermal Synthesis of AlPO₄-42 Molecular Sieves Rapidly at High Temperature