Citation: Zhang Tianyong, Liu Qian, Li Bin, Zhang Guoling, Chen Song, An Jing, Wang Shuhua. Study on Water Removal Control in Synthesis and Purification of Bisphenol S[J]. Chemistry, ;2016, 79(3): 259-263,237. shu

Study on Water Removal Control in Synthesis and Purification of Bisphenol S

Zhang Tianyong ¹ ,
Liu Qian ¹ ,
Li Bin ^1,, ,
Zhang Guoling ^2,3 ,
Chen Song ¹ ,
An Jing ² ,
Wang Shuhua ^2,3

1.
1. School of Chemical Engineering and Technology, Tianjin Key Laboratory of Applied Catalysis Science and Engineering, Tianjin University, Tianjin 300072;
2.
2. Kemai Chemical Co. Ltd., Tianjin 300270;
3.
3. Tianjin Enterprises Key Laboratory of Green Rubber Auxiliary, Tianjin 300270

Corresponding author: Li Bin,
Received Date: 1 July 2015
Available Online: 10 October 2015
Fund Project:

The effects of different refluxing and water removal time on the synthesis of bisphenol S are studied when one water distributor or two water distributors are installed. The water removal efficiency can be significantly improved with two water distributors. The refluxing time can be reduced and the crude yield can also be increased. The preferred conditions are as follows: 492.5g phenol, 500g mesitylene and 25g 2,6-naphthalene disulfonic acid are mixed, then 256g concentrated sulfuric acid is dropped, after which refluxing is kept for 6.5h. The crude yield is more than 99% and the mass fraction of bisphenol S is 96.69%. In the purification of bisphenol S, a single alcohol-mesitylene and mixed alcohol-mesitylene system are compared. Taking the cost, yield, color and other aspects into accounts, the mixed alcohol including isopropanol and isoamyl alcohol is better than a single isopropanol. In the selection of the decolorants, the activated carbon for sugar is much better. The preferred conditions of a single alcohol-mesitylene system are as follows: 11.1g crude wet product is dissolved in 44.4g isopropanol, after 66.6g mesitylene and 1.11g activated carbon for sugar are added, the whole system is stirred and decolored under 60℃ for 1h. The yield is 97.0% and the mass fraction of bisphenol S is 99.89%. The preferred conditions of mixed alcohol-mesitylene system are as follows：10g crude product is dissolved in 40g mixed alcohol(isopropanol:isoamyl alcohol=1:1), after 60g mesitylene and 1g activated carbon are added, the whole system is stirred and decolored under 60℃ for 1h. The final yield is 90.6% and the mass fraction of bisphenol S is 99.87%.
- Bisphenol S,
- Purification,
- Alcohol,
- Mesitylene
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