Citation: Liu E, Zhang Qiang, Dong Lifang, Jian Fangfang. Synthesis, Structure and Fluorescence Property of an Er(III) Complex of Isonicotinic Acid and 1,10-Phenanthrolin[J]. Chemistry, ;2016, 79(9): 839-843. shu

Synthesis, Structure and Fluorescence Property of an Er(III) Complex of Isonicotinic Acid and 1,10-Phenanthrolin

Liu E ^1,, ,
Zhang Qiang ² ,
Dong Lifang ³ ,
Jian Fangfang ⁴

1.
1. College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042;
2.
2. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042;
3.
3. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042;
4.
4. New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao 266042

Corresponding author: Liu E,
Received Date: 22 January 2016
Available Online: 2 March 2016

An Er(III) complex of Er(ina)₃(phen)·H₂O[ina=isonicotinic acid, phen=1,10-phenanthrolin] has been synthesized and characterized. X-ray single crystal diffraction reveals that, in the complex, the central Er(III) ion adopts an eight-coordinated distorted square anti-prism coordination geometry with O₆N₂ set, where one oxygen atom is from a water molecule and five oxygen atoms come from three ina ligands while two nitrogen atoms are from the phen ligand. In the crystal, two O-H…N hydrogen bonds along with a C-H…π and π…π supramoleuclar interactions fabricate 2D networks which further generate a 3D supramolecular architecture via interlayer π…π interactions and extensive C-H…O hydrogen bonds. Fluorescent spectra below 1000 nm show that the titled complex emits purple fluorescence.
- Er(III)complex,
- Isonicotinic acid,
- 1,10-Phenanthrolin,
- Hydrogen bond,
- Fluorescence
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