Home

Citation: Li Juan, Li Qingwen, Xia Xi. Synthesis of Nanosize MnO₂ by Solid State Reaction and Its Electrochemical Property Ⅲ.Synthesis and Performance of α-MnO₂[J]. Chinese Journal of Applied Chemistry, ;1999, 16(3): 103-105. shu

Synthesis of Nanosize MnO₂ by Solid State Reaction and Its Electrochemical Property Ⅲ.Synthesis and Performance of α-MnO₂

1.
Institute of Applied Chemistry, Xinjiang University, Urumqi 830046

Received Date: 23 November 1998
Available Online: 26 March 1999
Fund Project: 国家自然科学基金资助课题(29563007) (29563007)

Nanoparticles of α-MnO₂ were prepared by one-step solid state redox reaction at room temperature or 60℃. The solid state reaction was studied by XRD and TEM observation. It is shown that the time of grinding directly affected the crystalline type of the products from amorphous MnO₂ to unstable δ-MnO₂ and stable α-MnO₂. The reaction rate of KMnO₄ with MnCl₂·4H₂O was greater than that with Mn(Ac)₂·H₂O. The dischrge capacity of α-MnO₂ nanoparticles was larger than that of International Common Sample No.1 electrolytic MnO₂ especially in heavy load discharge.
- solid state redox reaction,
- nanoparticle,
- α-MnO₂,
- discharge performance
1. [1]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
2. [2]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
3. [3]
  Ao XIA , Botao YU , Jun CHEN , Guoqiang TAN . Preparation and electrochemical property of Ce-doped MnO₂. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2514-2526. doi: 10.11862/CJIC.20250163
4. [4]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
5. [5]
  Guangnan SHAN , Yuhui WANG , Yueru WU . Preparation and electrochemical performance of α-MnO₂ electrode material for aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 479-487. doi: 10.11862/CJIC.20250292
6. [6]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
7. [7]
  Zhen Li , Sujuan Zhang , Zhongliao Wang , Jinfeng Zhang , Gaoli Chen , Shifu Chen . Rational design of S-scheme CdS/MnO₂ heterojunctions for high-value photothermal synergistic catalytic oxidation of toluene. Acta Physico-Chimica Sinica, 2026, 42(4): 100179-0. doi: 10.1016/j.actphy.2025.100179
8. [8]
  Qingtao CHEN , Xiangdong SHI , Xianghai RAO , Liying JIANG , Chunxiao JIA , Fenghua CHEN . Catalytic and in situ surface-enhanced Raman scattering detection properties of graphene oxide/gold nanorod assembly. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 120-128. doi: 10.11862/CJIC.20250091
9. [9]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
10. [10]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
11. [11]
  Kun Chen , Huimin Lin , Xin Peng , Ziying Wu , Jingyue Dai , Yi Sun , Yaxuan Feng , Ziyi Huang , Zhiqiang Yu , Meng Yu , Guangyu Yao , Jigang Wang . In situ synthesis of MnO₂ micro/nano-adjuvants for enhanced immunotherapy of breast tumors. Chinese Chemical Letters, 2025, 36(5): 110045-. doi: 10.1016/j.cclet.2024.110045
12. [12]
  Haoting Wang , Mengfan Luo , Yuzhong Wang , Jialong Yin , Heng Zhang , Jia Zhao , Bo Lai . Mn(Ⅱ) enhanced permanganate oxidation of trace organic pollutants in water: Critical role of in situ formation of colloidal MnO₂. Chinese Chemical Letters, 2025, 36(6): 110348-. doi: 10.1016/j.cclet.2024.110348
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Mengdan Tian , Chuanzheng Zhu , Kun Luo . Hybrid organic-inorganic modification on tunnel-structured α-MnO₂ for high-performance aqueous zinc-ion battery. Chinese Chemical Letters, 2026, 37(3): 110702-. doi: 10.1016/j.cclet.2024.110702
15. [15]
  Jiaojiao Deng , Haocheng Li , Fei Zheng , Qingsong Weng , Yu Bai , Xiaoliang Yu , Qianlin Zhang , Qinghua Liang , Baohua Li . A “breathable” 3D lithium host with MnO₂ nanoflake array for long-lifespan anode-free lithium metal batteries. Chinese Chemical Letters, 2026, 37(3): 110681-. doi: 10.1016/j.cclet.2024.110681
16. [16]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
17. [17]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
18. [18]
  Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO₂ Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028
19. [19]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
20. [20]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(710)
HTML views(46)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Synthesis of Nanosize MnO2 by Solid State Reaction and Its Electrochemical Property Ⅲ.Synthesis and Performance of α-MnO2

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of Nanosize MnO₂ by Solid State Reaction and Its Electrochemical Property Ⅲ.Synthesis and Performance of α-MnO₂