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Citation: Gu Xiujun, Zhong Shunhe. Hydrodechlorination of 1, 2-Dichloropropane to Propene over Carbonized Resin Supported Nickel Catalyst[J]. Chinese Journal of Applied Chemistry, ;1999, 16(6): 5-8. shu

Hydrodechlorination of 1, 2-Dichloropropane to Propene over Carbonized Resin Supported Nickel Catalyst

Gu Xiujun ,
Zhong Shunhe

1.
College of Chemical Engineering and Technology, Tianjin University, Tianjin 300072

Received Date: 23 March 1999
Available Online: 24 August 1999

The carbonized resin support has been prepared.The Ni catalysts have been prepared by isometric impregnation of Ni(NO₃)₂ solution with carbonized resin support using ethylenediamine as solvent.Their superficial structures have been characterized by BET, SEM, XRD and TEM techniques.The reaction behavior of Ni supported on the carbonized resin in hydrodechlorination of 1, 2-dichloropropane to propene have been evaluated in a microreactor.The results show that the carbonized resin after activation has a specific area of 611 m²/g, the nickel supported on the resin has an average crystal size of 30 um and distributes uniformly.Over the activated carbonized resin supported nickel catalyst for hydrodechlorination of 1, 2-dichloropropane the latter has conversion more than 68% with the selectivity to propene being 100% under proper reaction conditions.
- dichloropropane,
- hydrodechlorination,
- propene,
- activated carbonized resin support,
- nickel catalyst
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