Citation:
YING Lai-Qiang, ZHAO Yu-Ying, BA Xiao-Wei, TANG Tao, JIN Ying-Tai. Polymerization of Acrylonitrile with Yttrocene-containing Aluminium Bimetallic Complex[J]. Chinese Journal of Applied Chemistry,
;2000, 17(5): 524-526.
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The polymerization of acrylonitrile was first studied using (C9H7)2Y(_-Et)2 AlEt2 as a single-component catalyst. The catalytic activity could be greatly increased when PhONa was added to the catalyst in amount of n(PhONa)/n(Cat)=3. A mechanism related to the polymerization initiation of AN is proposed.
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