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Citation: ZHOU Zhi-Bin, HE Hai-Ying, WENG Zhong-Yuan, ZHAO Cheng-Xue, QU Yan-Ling. Modification of SBS Polymers by Per(poly)fluoroalkylation[J]. Chinese Journal of Applied Chemistry, ;2000, 17(5): 516-519. shu

Modification of SBS Polymers by Per(poly)fluoroalkylation

1.
Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074

Received Date: 15 December 1999
Available Online: 8 May 2000

Poly(styrene-butadiene-styrene)(SBS) were modified by reacting with (R_fCO₂)₂ in CH₂Cl₂ at room temperature to give R_f-SBS polymers. All the fluoroalkylated products were characterized by IR and ¹⁹F NMR spectra. It is shown that R_f and R_fCO₂ groups were only added onto the double bonds of SBS polymer chain via single electron transfer(SET) mechanism. The R_f-SBS polymers showed good water- and oil-repellency and low refractive indices.
- SBS,
- per(poly) fluoroalkylation,
- per(poly )fluorodiacyl peroxide
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