Citation:
LIU Shi-Jun, ZENG Fan-Di, WANG Hai-Qiao. Synthesis and Characterization of Poly(2,5-dioctyloxy-1,4-phenylene)[J]. Chinese Journal of Applied Chemistry,
;2000, 17(5): 512-515.
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A blue electroluminescent polymer dioctyloxyl substituted polyparaphenylene(DOO-PPP) was synthesized in nitrobenzene via a chemical oxidative route using FeCl3 as catalyst. The effects of FeCl3 amount, temperature, reaction time and monomer concentration on the yield and moleclar weight of DOO-PPP were investigated. The polymer exhibited analogical thermogravimetric behavior both in air and N2, the peak wavelength of its photoluminescence spectrum in CHCl3 was at 426 nm.
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