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Citation: CAO Xu-Long, JIANG Sheng-Xiang, JIANG Xiao-Fang, LI Fang. On the Interaction Between Polyacrylamide and Anionic Surfactants[J]. Chinese Journal of Applied Chemistry, ;2002, 19(9): 866-869. shu

On the Interaction Between Polyacrylamide and Anionic Surfactants

1.
a Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
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b Geological Research Institute of Shengli Oilfield, SINOPEC, Dongying;
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c State University of New York at Buffalo, New York, 14260

Corresponding author: CAO Xu-Long,
Received Date: 17 January 2002
Available Online: 10 June 2002

The interactions between anionic surfactants(sodium laurate(C₁₁H₂₃COONa), sodium dodecyl sulfonate(C12AS)) and polyacrymide have been investigated by measurements of the reduced viscosity and ultra-violet spectra of the polymeric solutions. The results showed that in neutral and weak acid solutions PAM formed an aggregate with C₁₁H₂₃COONa behaved as a polyelectrolyte through hydrogen bonding and there was a large amount of charges in the PAM main chain caused by aggregate. However, PAM-C12AS aggregate was formed through dipolar interactions only in the case when the concentration of C12AS was higher than critical micelle concentration.
- polyacrylamide,
- surfactant,
- interaction,
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