引用本文:
冯云龙, 胡晓春, 孔黎春. 金刚烷甲酸铜(Ⅱ)配合物Cu(ada)2(py)2(H2O)的合成和晶体结构[J]. 应用化学,
2002, 19(11): 1109-1111.
Citation: FENG Yun-Long, HU Xiao-Chun, KONG Li-Chun. Synthesis and Crystal Structure of Adamantanecarboxylic Acid Complex with Cu(Ⅱ)[J]. Chinese Journal of Applied Chemistry, 2002, 19(11): 1109-1111.
Citation: FENG Yun-Long, HU Xiao-Chun, KONG Li-Chun. Synthesis and Crystal Structure of Adamantanecarboxylic Acid Complex with Cu(Ⅱ)[J]. Chinese Journal of Applied Chemistry, 2002, 19(11): 1109-1111.
金刚烷甲酸铜(Ⅱ)配合物Cu(ada)2(py)2(H2O)的合成和晶体结构
English
Synthesis and Crystal Structure of Adamantanecarboxylic Acid Complex with Cu(Ⅱ)
Abstract:
The crystal and molecular structure of the title complex, Cu(ada)2(py)2(H2O)(ada=adamantanecarboxylic group, py=pyridine), C32H42CuN2O5, were determined by XRD. It belongs to monoclinic system with space group P21/n and crystal cell parameters:a=1.6199(3), b=0.6805(1), c=2.8028(6) nm, U=94.15(3)°; V=3.082(1) nm3, Z=4, Dc=1.289 g/cm3, Mr=589.22, _(MoKT)=0.750 mm-1, F(000)=1 268. The structure was refined to R=0.0578 and wR=0.1581 for 4 447 observed reflections with I≥2e(I). The aquo complex is mononuclear with distorted square-pyramidal coordination.
-
Key words:
- copper complex
- / adamantanecarboxylic acid
- / synthesis
- / crystal structure
-
-
扫一扫看文章
计量
- PDF下载量: 1
- 文章访问数: 1119
- HTML全文浏览量: 132
下载:
