Citation:
YU Hai-Yin, WU Zheng-Cui, GUAN Ming-Yun, LING Qing, LI Shi-Feng, SUN Yi-Min. Graft Polymerization of MMA/BMA on the Surface of SiO2 Fine-particles and Its Application in PVC Composite Materials[J]. Chinese Journal of Applied Chemistry,
;2003, 20(10): 946-950.
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A kind of water-soluble hydroxyl propyl methyl cellulose(HPMC) has been encapsulated on the fine SiO2 particles, and some factors, such as pH value of the medium, encapsulation time and temperature were examined. The results showed that at~60℃ the highest amount of HPMC could be encapsulated on the SiO2 surface, and it increased with increase of time and decrease of pH value. The graft copolymerization of methylmethacrylate(MMA) and butylmethacrylate(BMA) has been carried out on the surface of SiO2/HPMC particles successfully. Encapsulated SiO2 particles being dispersed in PVC have higher impact strength and tensile strength than that of control SiO2 sample in 42.3% and 41%, respectively.
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