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Citation: YU Yan, FU Zai-Hui, YIN Du-Lin, XU You-Zhi, XU Qiong, WU Jing, TAN Fu-Qiang. Etherification of Cathchol with Methanol over ZnCl₂/NaY[J]. Chinese Journal of Applied Chemistry, ;2004, 21(7): 664-668. shu

Etherification of Cathchol with Methanol over ZnCl₂/NaY

1.
College of Chemistry and Chemical Engineering, Hu'nan Normal University, Changsha 410081

Corresponding author: FU Zai-Hui,
Received Date: 27 August 2003
Available Online: 16 November 2003
Fund Project: 国家自然科学基金(29773013) (29773013)

ZnCl₂ modified NaY solid L-acid catalysts were prepared by solid-state reaction and characterized by XRD and NH₃-TPD.The Zn content in the catalysts was determined by ICP-AES.The catalytic properties of the catalysts in the etherification of cathechol with methanol were examined in a fixed bed micro-reactor.The results indicated that ZnCl₂ modified NaY showed higher catalytic activity than HY with B acid sites in etherification.In the optimum reaction conditions,the conversion of catechol and the selectivity for guaiacol over ZnCl₂(10%)/NaY were up to 86.7% and 99.3% respectively.
- ZnCl₂/NaY,
- solid acid catalyst,
- etherification,
- catechol,
- methanol,
- guaiacol
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沈阳化工大学材料科学与工程学院沈阳 110142

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Etherification of Cathchol with Methanol over ZnCl₂/NaY