引用本文:
牛永生, 邱明艳, 李建平. 芳酰基芳基偶氮化合物的合成[J]. 应用化学,
2005, 22(1): 108-110.
Citation: NIU Yong-Sheng, QIU Ming-Yan, LI Jian-Ping. Synthesis of Arylacyl-aryl diazene Compounds[J]. Chinese Journal of Applied Chemistry, 2005, 22(1): 108-110.
Citation: NIU Yong-Sheng, QIU Ming-Yan, LI Jian-Ping. Synthesis of Arylacyl-aryl diazene Compounds[J]. Chinese Journal of Applied Chemistry, 2005, 22(1): 108-110.
芳酰基芳基偶氮化合物的合成
摘要:
偶氮化合物广泛用作染料、分析试剂[1]、非线性光学材料、激光盘信息存储材料和现代彩色照相技术中的油溶性染料。偶氮苯衍生物具有很好的光电性能[2]。近年来许多研究表明,一些偶氮液晶膜具有热释电和压电效应,可用于制备各种滤色器、光电设备、光敏感元件、光电池、电子发光设备中的释电薄膜等[3]。
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关键词:
- 芳酰基芳基偶氮化合物
- / 哌啶氮氧自由基
- / 芳酰基芳肼
- / 相转移催化
English
Synthesis of Arylacyl-aryl diazene Compounds
Abstract:
Ten arylacyl-aryl diazene compounds were synthesized in yields of 89.6%~95.6% under mild conditions with 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as phase-transfer catalyst in dehydrogenation of arylacyl-arylhydrazines. Their structures were confirmed by elemental analysis, IR and 1H NMR spectra. The reaction mechanism was discussed.
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