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Citation: WANG Rui-Fang, SHI Zuo-Qing, SHI Rong-Fu, ZHANG Jing-Ze, YANG Wen-Hong, WU Wei. Preparation of Aminated Macroporous Hypercrosslinked Resins and Their Application in Chromatographic Separation of Camptothecin and Vincoside-Lactam[J]. Chinese Journal of Applied Chemistry, ;2005, 22(1): 24-29. shu

Preparation of Aminated Macroporous Hypercrosslinked Resins and Their Application in Chromatographic Separation of Camptothecin and Vincoside-Lactam

1.
a State Key Laboratory of Functional Polymeric Materials for Adorption Separation, Institute of Polymer Chemistry, NanKai University, Tianjin 300071;
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b Suntar Membrane Technology (Xiamen) CO., Ltd, Xiamen

Corresponding author: SHI Zuo-Qing,
Received Date: 26 March 2004
Available Online: 16 July 2004
Fund Project: 国家自然科学基金(20174017)资助项目 (20174017)

Macroporous hypercrosslinked resin(Rf18) was synthesized from styrene and decorated by loading methyiamine(Rs3), N-methylacetamido(Rs4), dimethylamine(Rs5) and trimethylamine(Rs6) respectively. The adsorption and chromatographic separation of camptothecin and Vincoside-Lactam(VCS-LT) by the synthesized resins were compared. Their adsorption capacity and adsorption selectivity for camptothecin and vincoside-lactam were found to be remarkably increased. For quaternary ammonium resin(Rs6), the separation impact(α_c/v) was 114. Camptothecin and vincoside-lactam could be effectively separated with resins Rf18 (Rs3, Rs5). But camptothecin could not be washed out from Rs6 with organic solvent, it could be easily washed out with acidic solution of 80% ethanol-water(pH=4).
- camptothecin,
- Vincoside-Lactam,
- aminated-macroporous hypercrosslinked resin,
- adsorption performance,
- chromatographic separation
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