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Citation: ZHAO Xiao-Wei, ZHAO Tao, ZHANG Ji-Wei, ZHANG Lei, CUI Yuan-Chen. Catalytic Property of Polyvinyl Chloride-Polyethylene Polyamine Supported Palladium Complex for Suzuki Reaction[J]. Chinese Journal of Applied Chemistry, ;2006, 23(7): 815-817. shu

Catalytic Property of Polyvinyl Chloride-Polyethylene Polyamine Supported Palladium Complex for Suzuki Reaction

1.
a College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001;
2.
b Laboratory of Special Functional Materials, Henan University, Kaifeng

Corresponding author: CUI Yuan-Chen,
Received Date: 22 July 2005
Available Online: 22 November 2005

Polyvinyl chloride triethylene tetraamine palladium complex(PVC-TETA-Pd) was prepared,and its catalytic property for Suzuki reaction under different conditions was discussed.The results showed that this complex could catalyze the Suzuki reaction of sodium tetraphenylborate with iodobenzene to form biphenyl in air.The reaction conditions were optimized,i.e.,NaHCO₃was used as base and a mixture with a ratio of V(DMF):)V(H₂O) being 2:1 was used as solvent.This complex can be reused for several times.
- Suzuki reaction,
- catalysis,
- PVC-TETA-Pd,
- sodium tetraphenylborate
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