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Citation: ZHOU Jie, YANG Yi-Wen, REN Qi-Long. Adsorption and Separation Properties of Mono-6-deoxy-6-(p-tolysulfonyl)-β-cyclodextrin on the Macroporous Resins[J]. Chinese Journal of Applied Chemistry, ;2006, 23(8): 821-825. shu

Adsorption and Separation Properties of Mono-6-deoxy-6-(p-tolysulfonyl)-β-cyclodextrin on the Macroporous Resins

1.
National Laboratory of Secondary Resources Chemical Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: ZHOU Jie,
Received Date: 31 August 2005
Available Online: 28 November 2005
Fund Project: 教育部高等学校博士学科点专项科研基金项目(20040335045) (20040335045)

Seventeen resins were selected to compare their performances in adsorbing and desorbing monosubstituent in the mixture.Experimental results showed that HZ-841 resin possessed higher selectivity and desorption capacity.The adsorption characteristic of monosubstituent on HZ-841 resin was determined.The adsorption isotherms,kinetic curves,breakthrough curves and elution curves were determined.The adsorption isotherms were Langmuir type.The adsorption kinetic curve could be preferably described by the second-order Lagergren equation,and the adsorption equilibrium was achieved in about 5 h.On a column of Φ 16 mm×400 mm,the breakthrough volume of CD was 200 mL when the mixture concentration was 4.8 g/L,the flow rate was 2.5 mL/min,while that of monosubstituent was 1 130 mL.The adsorbate was completely eluted with 700 mL of hot(90℃) water,and the desorption rates were 98.1% and 94.9% for β-cyclodextrin and monosubstituent,respectively.
- Mono-deoxy-(p-tolysulfonyl)-β-cyclodextrin,
- resin,
- adsorption,
- separation
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