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Citation: ZHU Tie-Quana, WANG Chang-Sui, WANG Hong-Min, MAO Zhen-Wei, GONG Ming, WU Xiao-Song, HONG Gang. Analysis on the “Silvery Glaze” of Green Glazed Pottery of Song Dynasty and Its Formation Mechanism[J]. Chinese Journal of Applied Chemistry, ;2007, 24(9): 977-981. shu

Analysis on the “Silvery Glaze” of Green Glazed Pottery of Song Dynasty and Its Formation Mechanism

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a Archeaometry Lab of University of Science and Technology of China, Hefei 230026;
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b Graduate College of Chinese Academy of Sciences, Beijing;
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c School of Engineering Sciences of USTC, Hefei;
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d Huanggang Municipal Museum, Huanggang

Corresponding author: ZHU Tie-Quana,
Received Date: 9 September 2006
Available Online: 9 March 2007
Fund Project: 国家自然科学基金资助项目(19975046) (19975046)中国科学院创新工程(KJCX-No4) (KJCX-No4)教育部"985工程"(985-2-201) (985-2-201)

Silvery glaze is a kind of common disease covered on the surface of ancient lead glazed ceramics. Using analytical methods of SEM-EDS, XRD, FTIR, XPS, a piece of green glazed pottery of Song dynasty excavated from Huanggang area, Hubei province, was analyzed. The analysis indicates that the silvery glaze is in high content of calcium(Ca:5.1%~10.3%), phosphor(P:4.6%~9.2%) and lead(Pb:56.9%~70.5%), which was mainly in crystalline phase of Pb_10-xCa_x(PO₄)(OH)₂(x<2.7). In addition, elements of iron(Fe:2.5%~3.8%) and chlorine (Cl:1.8%~2.1%) were detected in the area of brown and yellow of the silvery glaze. Due to the local burial circumstance of weak acid, the silvery glaze is the result from the chemical reaction between the lead ion in the glaze of pottery and all kinds of phosphate compound in the soil.
- green glaze pottery,
- silvery glaze,
- calcium lead phosphate,
- phosphate
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