Home

Citation: FEI Xue-Ning, YANG Shao-Bin, LIU Li-Juan, SHI Bo-Jie, ZHANG Bao-Lian. Study on Ullmann Condensation Reaction of Bromamine Acid[J]. Chinese Journal of Applied Chemistry, ;2007, 24(10): 1136-1139. shu

Study on Ullmann Condensation Reaction of Bromamine Acid

1.
Department of Material Science and Engineering, Tianjin Institute of Urban Construction, Tianjin 300384

Corresponding author: FEI Xue-Ning,
Received Date: 28 October 2006
Available Online: 8 February 2007
Fund Project: 教育部科学技术重点资助项目(205013) (205013)

The catalytic system of sulfuric acid-water-copper used in Ullmann condensation reaction of bromamine acid was replaced with a strong acid ion exchange resin-ethanol-copper system. The effect of the ion exchange resin loading, the kind of solvent, and the reaction temperature on the yield of the condensation product was investigated. The results show that the yield of the condensation product could reach 94.0% in ethanol-water(9:1) at 70℃ after 3 h. The strong acid ion exchange resin, copper powder and ethanol could be reused under the reaction conditions. The activity of the resin was not obviously reduced after reusing 5 times, and 70%~80% ethanol and 85%~90% copper powder in the reaction can be recovered.
- strong acid ion exchange resins,
- Ullmann condensation,
- amino-bromoanthraquinone-sulfonic sodium,
- C.I pigment red 177 intermediate
1. [1]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
2. [2]
  Lingyu Chang , Yanfang Lang , Yuyan Zhu , Jie Wang , Ying Guo , Die Wang , Peng Ding , Yueming Zhou , Zhixiang Gong , Shujuan Liu . Machine Learning-Optimized Microcolumn Ion Exchange Chromatography for Trace Arsenic Determination. University Chemistry, 2026, 41(1): 76-84. doi: 10.12461/PKU.DXHX202506023
3. [3]
  Lin LI , Jiaxue LI , Meixia YANG , Jiayu DING , Jiaqi JING , Ruiping ZHANG . Preparation of mitoxantrone self-assembled carrier-free nanodrugs regulated by sodium acetate for apoptosis induction of human breast carcinoma cells. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2536-2548. doi: 10.11862/CJIC.20250138
4. [4]
  Zhilian Liu , Wengui Wang , Hongxiao Yang , Yu Cui , Shoufeng Wang . Ideological and Political Education Design for the Synthesis of Irinotecan Drug Intermediate 7-Ethyl Camptothecin. University Chemistry, 2024, 39(2): 89-93. doi: 10.3866/PKU.DXHX202306012
5. [5]
  Yuhang Zhang , Yi Li , Yuehan Cao , Yingjie Shuai , Yu Zhou , Ying Zhou . Regulating the formation type by Ir of intermediates to suppress product overoxidation in photocatalytic methane conversion. Acta Physico-Chimica Sinica, 2026, 42(2): 100173-0. doi: 10.1016/j.actphy.2025.100173
6. [6]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
7. [7]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
8. [8]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-0. doi: 10.3866/PKU.WHXB202312007
9. [9]
  Yinwu Su , Xuanwen Zheng , Jianghui Du , Boda Li , Tao Wang , Zhiyan Huang . Green Synthesis of 1,3-Dibromoacetone Using Halogen Exchange Method: Recommending a Basic Organic Synthesis Teaching Experiment. University Chemistry, 2024, 39(5): 307-314. doi: 10.3866/PKU.DXHX202311092
10. [10]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
11. [11]
  Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
12. [12]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
13. [13]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-0. doi: 10.3866/PKU.WHXB202310013
14. [14]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
15. [15]
  Huilin Li , Qi Ma , Jin Li , Zihan Yu , Xingyu Liu , Ziyan Zhu , Yuhuan Fu , Junlong Zhao . Red Umbrella as a Bridal Gift: Unveiling the Chemical Secrets of Oil-Paper Umbrella Craftsmanship. University Chemistry, 2026, 41(2): 301-306. doi: 10.12461/PKU.DXHX202502108
16. [16]
  Junyang FENG , Xiaoli HAN , Yongjie SONG , Gang LI . Proton conduction and fluorescence properties of an ionic hydrogen-bonded organic framework constructed from dibromophthalic acid. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 693-702. doi: 10.11862/CJIC.20250350
17. [17]
  Peicai Li , Xubin Wang , Qinghua Zhang , Bowen Wang , Xiaohui Rong , Yong-Sheng Hu , Zhongtao Li . High-rate and long-cycling P2-type cathode material for sodium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(5): 100214-0. doi: 10.1016/j.actphy.2025.100214
18. [18]
  Qu ZHANG , Tao WANG , Yinying WANG , Bo LI , Dongling WU . Synthesis of amino acid-functionalized nitrogen-doped carbon dots/cuprous oxidecomposite material and its performance in aqueous zinc-ion batteries. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 488-498. doi: 10.11862/CJIC.20250272
19. [19]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
20. [20]
  Jing Tan , Bo Zheng , Lingyan Gao . Application of Crown Ether-Based Artificial Ion Transporters. University Chemistry, 2026, 41(2): 232-237. doi: 10.12461/PKU.DXHX202501010

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1408)
HTML views(154)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return