Home

Citation: ZHANG Fa-Ai, ZHU Xing-Hua. Emulsion Polymerization of 2-Hydroxyethyl Methacrylate[J]. Chinese Journal of Applied Chemistry, ;2008, 25(5): 592-595. shu

Emulsion Polymerization of 2-Hydroxyethyl Methacrylate

ZHANG Fa-Ai ^, ,
ZHU Xing-Hua

1.
Department of Material and Chemical Engineering, Guilin University of Technology, Guilin 541004

Corresponding author: ZHANG Fa-Ai,
Received Date: 2 May 2007
Available Online: 25 July 2007
Fund Project: 新材料及其制备新技术广西区重点实验室资助课题(桂科能063006-5C-06) (桂科能063006-5C-06)

The effects of initiator system,emulsifier type and amount,reaction temperature,and electrolyte on monomer conversion,coagulum content,particle size and distribution for the emulsion polymerization of the water-soluble 2-hydroxyethyl methacrylate (HEMA) were investigated.The results showed the oil-soluble initiator azoisobutyronitrile (AIBN) may increase the monomer conversion and decrease the coagulum;the amount of the emulsifier had little effect on the monomer conversion,but the coagulum greatly decreased with the increase of the amount of the emulsifier.As the reaction temperature increased from 65℃ to 85℃,the monomer conversion increased first and then decreased,and the coagulum increased continuously,and the ideal reaction temperature was 75℃.The presence of electrolyte,NaHCO₃,decreased the monomer conversion;the particle distribution index was broader and multimodal distributions were observed.
- hydroxyethyl methacrylate,
- emulsion polymerization,
- monomer conversion,
- coagulum,
- particle size and distribution
1. [1]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
2. [2]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-0. doi: 10.3866/PKU.WHXB202309041
3. [3]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
4. [4]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
5. [5]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
6. [6]
  Wan Li , Xiaohang Qiu , Xiuyun Wang , Mei Shi , Xiuqiong Zeng , Yanping Ren , Faqiong Zhao , Min Hu , Yiru Wang , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Wenwei Zhang , Weihong Li , Yong Fan , Jianrong Zhang , Shuyong Zhang . Specifications of Laboratory Water and Suggestions on the Use of Conductivity Meter. University Chemistry, 2026, 41(3): 77-86. doi: 10.12461/PKU.DXHX202507036
7. [7]
  Fangyan Zhang , Yuhan Li , Bowen He , Meng Lin , Ying Ma . Determination of Sodium Carbonate Content: A Conductometric Titration Approach. University Chemistry, 2026, 41(3): 373-380. doi: 10.12461/PKU.DXHX202505023
8. [8]
  Yan Long , Wenbo Zhao , Qing Cao , Xiangyu Li , Fukui Li , Yanwei Hu , Shiyu Song , Kaikai Liu . Phosphorescent carbon nanodot inks for scalable and high-resolution invisible printing. Acta Physico-Chimica Sinica, 2026, 42(3): 100198-0. doi: 10.1016/j.actphy.2025.100198
9. [9]
  Chunfang Zhang , Cuimiao Zhang , Shuai Liu , Yaduo Zheng , Lin Yang , Kehan Jiang , Mingtao Run . Refined Experiment for Magnetic Susceptibility Determination: A Digital Empowered Experiment Based on WeChat Mini Program and Animated Video. University Chemistry, 2026, 41(1): 244-252. doi: 10.12461/PKU.DXHX202505056
10. [10]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
11. [11]
  Wen Tang , Luyu Sui , Qian Chen , Jun Shao , Xinwen Peng , Jianwen Jiang , Shuiliang Chen . Project-based Teaching of “the Condensed State of Polymers”: Unveiling the Lithium-Ion Battery Separator. University Chemistry, 2025, 40(11): 115-126. doi: 10.12461/PKU.DXHX202412108
12. [12]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
13. [13]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
14. [14]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
15. [15]
  Shuting KONG , Fengshi ZHANG , Zhiyi LU , Yanling LIU , Minglang YE , Zhengfang HU , Longsheng WANG , Bing HU , Haiying WANG . Research advance of the preparation of tributyl citrate catalyzed by supported heteropolyacid catalysts. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 441-452. doi: 10.11862/CJIC.20250303
16. [16]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
17. [17]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
18. [18]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077
19. [19]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
20. [20]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1112)
HTML views(273)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return