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Citation: XU Wei-Xia, ZHANG You-Ming, WEI Tai-Bao. Synthesis of Bis-arylthiosemicarbazone Receptors and Their Anion Recognition Properties[J]. Chinese Journal of Applied Chemistry, ;2008, 25(12): 1460-1463. shu

Synthesis of Bis-arylthiosemicarbazone Receptors and Their Anion Recognition Properties

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a The Department of Chemistry of Xianyang Normal University, Xianyang 712000;
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b Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: ZHANG You-Ming,
Received Date: 12 November 2007
Available Online: 20 January 2008
Fund Project: 咸阳师范学院科研专项基金(06XSYK258)资助项目 (06XSYK258)

Two new bis-arylthiosemicarbazone receptors were designed and synthesized.The binding properties of the receptors with anions such as F^-,Cl^-,Br^-,I^-,CH₃COO^-,HSO₄^-,H₂PO₄^- and NO₃^- in DMSO were investigated by UV-Vis spectroscopy.A clear color change from colorless to yellow was observed upon addition of NO₃^-,CH₃COO^-or H₂PO₄^- to the solution of the two receptors in DMSO by naked-eyes.The results show that the two receptors have a better selectivity forF^-,CH₃COO^-and H₂PO₄^-,but exhibit no evident binding with Cl^-,Br^-,I^-,HSO₄^- and NO₃^-.The data show that the two receptors have different binding abilities with the three anions.For the same anion,the association constants show the trend:receptor S₁>receptor S₂.The UV-Vis data indicate that a 1:1 stoichiometry complex is formed between the receptors and the three anions.Solvation effect confirmed the hydrogen bonding interactions between the receptors and anions.
- bis-arylthiosemicarbazone,
- synthesis,
- anion recognition,
- hydrogen-bonding interaction
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