Citation: WU Qiong-Jie, CHEN Xiao-Hua, CAI Bi-Qiong, WU Dan. Synthesis and Crystal Structure of Trinuclear Nickel(Ⅱ) Complex with N-Acetylsalicylhydrazide and Imidazole Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2650-2654. shu

Synthesis and Crystal Structure of Trinuclear Nickel(Ⅱ) Complex with N-Acetylsalicylhydrazide and Imidazole Ligands

1.
1. College of Life Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China;

Corresponding author: WU Qiong-Jie,
Received Date: 28 March 2012
Available Online: 17 September 2012
Fund Project: 福建农林大学校青年教师基金(No.08B10) (No.08B10)福建省教育厅科技项目(No.JB10007)资助项目. (No.JB10007)

Employing N-acetylsalicylhydrazide (H₃ashz), imidazole (imdz) as mixed ligands, a new trinuclear nickel(Ⅱ) compound [Ni₃(ashz)₂(imdz)₂]·2DMF has been synthesized and characterized by elemental analysis, IR and X-ray diffraction structural analysis. Crystal data: monoclinic, space group P2_1/n with a=1.028 0(2) nm, b=1.499 2(3) nm, c=1.523 1(5) nm, β=114.16(2)°, V=2.140 1(9) nm³, Z=2, D_c=1.516 g·cm^-3, μ=1.372 mm^-1, F(000)= 1 012. In the title complex, two μ₂-bridged ashz3- ligands bound to three nickel centers in a linear array. The three nickel atoms are directly linked together by two trans diazine (N-N) bridges, with the neighboring nickel atomic separations of 0.462(1) nm. CCDC: 902486.
- nickel(Ⅱ) complex;synthesis;crystal structure;thermal stability analysis
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沈阳化工大学材料科学与工程学院沈阳 110142