Citation: NIE Xu-Liang, XIONG Hui, TU Yong-Gang, HUANG Chang-Gan. Synthesis and Crystal Structures of Complexes of Copper, Silver Assembled by Diniconazole[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2593-2596. shu

Synthesis and Crystal Structures of Complexes of Copper, Silver Assembled by Diniconazole

1.
1. College of Science, Jiangxi Agricultural University, Nanchang 330045, China;

Corresponding author: HUANG Chang-Gan,
Received Date: 12 April 2012
Available Online: 15 July 2012
Fund Project: 国家自然科学基金(No.30760021) (No.30760021)江西省自然科学基金(No.0530016) (No.0530016)江西省教育厅青年基金(No.GJ10421)资助项目. (No.GJ10421)

Two new complexes [CuL₄Cl₂] (1) and [AgL₂]NO₃ (2) (L=diniconazole) were synthesized by solvothermal condition and structurally characterized by element analysis, IR and single crystal X-ray diffraction. Complex 1 is the Triclinic system, space group P1 with a=0.882 3(7) nm, b=1.370 5(10) nm, c=1.516 4(11) nm, α=91.507(11)°, β=97.356(9)°, γ=107.683(9)°. Complex 2 belongs to the Monoclinic system, space group P2_1/c with a=1.229 2(3) nm, b=1.272 1(3) nm, c=2.431 7(5) nm, α=90°, β=98.694(3)°, γ=90°. 1 and 2 are linked into a one dimensional chain by intermolecular hydrogen bonds. CCDC: 805738, 1; 818240, 2.
- copper complex;silver complex;diniconazole;hydrothermal synthesis;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142