Citation: HU Bing, YAO Xiao-Qiang, LU Yan-Yun, ZHANG You-Ming, WEI Tai-Bao. Synthesis of Zinc(Ⅱ) Complex of [5-Amino-1,3,4-thiadiazol-2-yl]thioglycolic and the Study of Its Crystal Structure and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2581-2586. shu

Synthesis of Zinc(Ⅱ) Complex of [5-Amino-1,3,4-thiadiazol-2-yl]thioglycolic and the Study of Its Crystal Structure and Properties

1.
1. Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China; Key Laboratory of Polymer Materials of Gansu Province; College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;

Corresponding author: WEI Tai-Bao,
Received Date: 28 December 2011
Available Online: 12 September 2012
Fund Project: 国家自然科学基金(No.21064006,21161018,21262032) (No.21064006,21161018,21262032)甘肃省自然科学基金(No.1010RJZA018) (No.1010RJZA018)

A complex of Zinc(Ⅱ), [Zn(atma)₂]_n in which the Hatma=[5-amino-1,3,4-thiadiazol-2-yl]thioglycolic acid has been synthesized and structurally characterized. The structure of the complex was determined by IR, TGA, elemental analysis and single crystal X-ray diffraction. In crystal, the title compound self-assembled from 2D layers to 3D surpramolecular framework by π-π interaction, hydrogen bonding and intercalation of groups. The cyclic voltammetry behaviors of the complex on glass carbon electrode showed a typical irreversible process. The antibacterial assays indicate that the complex shows better activities than ligand. CCDC: 805509.
- coordination polymer;crystal structure;cyclic voltammetry;antibacterial
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