Citation: MAO Jun-Xian, JIANG Jiao, WANG Hua-Kai, YANG Li-Jun, WANG Yang-Nian, GENG Jiao, WANG Xi-Zhang, HU Zheng. Immobilizing Ruthenium Nanoparticles onto Nitrogen-Doped Carbon Nanotubes for Aerobic Oxidation of Benzyl Alcohol under Ambient Pressure[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2508-2512. shu

Immobilizing Ruthenium Nanoparticles onto Nitrogen-Doped Carbon Nanotubes for Aerobic Oxidation of Benzyl Alcohol under Ambient Pressure

1.
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: GENG Jiao, WANG Xi-Zhang,
Received Date: 8 May 2012
Available Online: 1 July 2012
Fund Project: 国家自然科学基金(No.21173114,21173115,20833002) (No.21173114,21173115,20833002) “973”项目(No.2007CB936302) (No.2007CB936302)江苏省自然科学基金(No.BK2010304)资助项目. (No.BK2010304)

Ruthenium nanoparticles were conveniently immobilized on nitrogen-doped carbon nanotubes (NCNTs) via microwave-assisted ethylene glycol reduction. Ru/NCNTs catalysts presented the excellent catalytic performance and cyclical stability for the aerobic oxidation of benzyl alcohol under atmospheric condition, compared with the catalysts supported on carbon nanotubes (CNTs) and activated carbon (AC). The conversion of benzyl alcohol could rearch 93% and the selectivity of benzaldehyde was higher than 99% at 90 ℃. The doped nitrogen atoms embedded in the NCNTs wall are responsible for the improved catalytic performance.
- oxidation of benzyl alcohol;nitrogen-doped carbon nanotubes;Ru nanoparticles;microwave-assisted ethylene glycol reduction
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沈阳化工大学材料科学与工程学院沈阳 110142