Citation: YANG Quan, LIU Ying-shu, LI Zi-yi, YANG Xiong, WANG Zhan-ying, JIANG Li-jun. Study on the adsorption behaviours of naphthalene on MCM-41 and SBA-15 mesoporous molecular sieves[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1482-1488. shu

Study on the adsorption behaviours of naphthalene on MCM-41 and SBA-15 mesoporous molecular sieves

YANG Quan ¹ ,
LIU Ying-shu ^1,2 ,
LI Zi-yi ¹ ,
YANG Xiong ^1,2,, ,
WANG Zhan-ying ¹ ,
JIANG Li-jun ¹

1.
1. School of Mechanical Engineering, University of Science and Technology Beijing, Beijing 100083, China;;

Corresponding author: YANG Xiong,
Received Date: 4 June 2015
Available Online: 1 August 2015
Fund Project: 国家自然科学基金(51478038)资助项目 (51478038)

In this paper, the adsorption behaviours of naphthalene on two popular mesoporous molecular sieves, SBA-15 and MCM-41 were studied. The adsorption isotherms were obtained, and fitted with isotherm models of Langmuir, Freundlich and D-R. The breakthrough curves of naphthalene at different initial concentrations were measured, and well predicted by the constant-pattern wave model. Results show that the Langmuir model can well describe the adsorption isotherms of naphthalene at low concentration with R² higher than 99%. The adsorption ability of SBA-15 with a microporous structure is stronger than that of MCM-41 which contains only mesoporous structures. The predictions on breakthrough curves by the constant-pattern model exhibited higher correlation coefficient for SBA-15 than for MCM-41.The overall mass transfer coefficient K_a of naphthalene on SBA-15 is higher than that on MCM-41, indicating that there is a lower mass transfer resistance and the mass transfer equilibrium can be achieved faster over SBA-15.
- MCM-41,
- SBA-15,
- naphthalene,
- adsorption isotherm,
- breakthrough curve
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