Citation: ZENG Zhi-wei, ZOU Jun, YANG Hai-ping, WANG Xian-hua, WU Chun-fei, PT William, CHEN Han-ping. Influence of potassium on the performance of nickel-based catalyst in the steam gasification of cellulose[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1433-1438. shu

Influence of potassium on the performance of nickel-based catalyst in the steam gasification of cellulose

1.
1. State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China;

Corresponding author: YANG Hai-ping,
Received Date: 13 May 2015
Available Online: 5 August 2015
Fund Project: 国家自然科学基金(51376076,51306066) (51376076,51306066)国家重点基础研究发展规划(973计划,2013CB228102)资助项目 (973计划,2013CB228102)

The influence of alkali metal volatilization on the performance of nickel-based catalyst in the steam gasification of cellulose biomass was investigated in a two-stage fixed bed reactor. The results show that potassium is deposited on the catalyst surface with the volatilization of potassium salt during the catalytic steam reforming of potassium-loaded cellulose. The existence and deposition of proper amount of potassium may suppress the coke deposition and enhance the activity of nickel-based catalyst, which is of benefit to producing more hydrogen in the steam gasification of biomass. However, excessive amount of potassium loaded in cellulose may reduce the activity of nickel-based catalyst; moreover, with the repetitious operations, potassium is accumulated on the catalyst surface, which may lead to an obvious inhibitory effect on the activity and stability of nickel-based catalyst in the steam gasification of biomass.
- alkali metals,
- nickel-based catalyst,
- cellulose,
- steam gasification
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