Citation: WANG Bin, ZHANG Qiang, LI Chun-yi, SHAN Hong-hong. Study on the preliminary cracking of heavy vacuum gas oil: Effect of acid type and contacting order of Lewis and Brönsted sites of matrices on the yield of LPG olefins[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(11): 1350-1358. shu

Study on the preliminary cracking of heavy vacuum gas oil: Effect of acid type and contacting order of Lewis and Brönsted sites of matrices on the yield of LPG olefins

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State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: LI Chun-yi,
Received Date: 27 May 2015
Available Online: 2 August 2015
Fund Project: 国家自然科学基金(U1462205,21406270) (U1462205,21406270)研究生创新工程(YCX2015028) (YCX2015028)中央高校基本科研业务费专项资金(15CX06036A) (15CX06036A)青岛市民生计划(13-1-3-126-nsh)资助项目 (13-1-3-126-nsh)

A series of alumina with similar textural properties but different acidities were prepared and used as the matrix components of the FCC catalysts. The effect of acid type of matrices and contacting order of acid sites of different types on the yield of LPG olefins in catalytic cracking of heavy vacuum gas oil (HVGO) was investigated. The results showed that the matrix is more conductive to the formation of LPG olefins from the aspect of reaction route, in comparison with the REUSY molecular sieves. When there are Brönsted acidity on the matrix surface and/or HVGO molecules first contact with Lewis acid sites and then react with Brönsted acid sites during the matrix-precracking process, cracking reactions are enhanced while hydrogen transfer reactions are restricted, which facilitate to increase the yield of LPG olefins.
- fluid catalytic cracking,
- preliminary cracking,
- matrix,
- surface acidity,
- acid type,
- contacting order
1. [1]
  [1] LI C, YANG C, SHAN H. Maximizing propylene yield by two-stage riser catalytic cracking of heavy oil[J]. Ind Eng Chem Res, 2007, 46(14): 4914-4920.
2. [2]
  [2] CORMA A, MELO F V, SAUVANAUD L, ORTEGA F. Light cracked naphtha processing: Controlling chemistry for maximum propylene production[J]. Catal Today, 2005, 107-108: 699-706.
3. [3]
  [3] CORMA A, FARALDOS M, MARTINEZ A, MIFSUD A. Hydrogen transfer on USY zeolites during gas oil cracking: Influence of the adsorption characteristics of the zeolite catalysts[J]. J Catal, 1990, 122(2): 230-239.
4. [4]
  [4] OTTERSTEDT J E, ZHUY, STERTE J. Catalytic cracking of heavy oil over catalysts containing different types of zeolite Y in active and inactive matrices[J]. Appl Catal, 1988, 38(1): 143-155.
5. [5]
  [5] FENG R, LIU S, BAI P, QIAO K, WANG Y H, MEGREN M J, YAN Z F. Preparation and characterization of γ-Al₂O₃ with rich Brönsted acid sites and its application in the fluid catalytic cracking process[J]. J Phys Chem C, 2014, 118(12): 6226-6234.
6. [6]
  [6] XU S, ZHANG Q, FENG Z, MENG X, ZHAO T, LI C, YANG C, SHAN H. A high-surface-area silicoaluminophosphate material rich in Brönsted acid sites as a matrix in catalytic cracking[J]. J Nat Gas Chem, 2012, 21(6): 685-693.
7. [7]
  [7] HOLLAND B T, SUBRAMANI V, GANGWAL S K. Utilizing colloidal silica and aluminum-doped colloidal silica as a binder in FCC catalysts: Effects on porosity, acidity, and microactivity[J]. Ind Eng Chem Res, 2007, 46(13): 4486-4496.
8. [8]
  [8] CHEN W, HAN D, SUN X, LI C. Studies on the preliminary cracking of heavy oils: Contributions of various factors[J]. Fuel, 2013, 106: 498-504.
9. [9]
  [9] WANG B, HAN C, ZHANG Q, LI C,YANG C, SHAN H, Studies on the preliminary cracking of heany oils: The effect of matrix acidity and a proposal of a new reaction route[J]. Energy Fuels, 2015, doi: 10.1021/acs.energyfuels.5b01280.
10. [10]
  [10] CORMA A, MIGUEL P J, ORCHILLES A V. The role of reaction temperature and cracking catalyst characteristics in determining the relative rates of protolytic cracking, chain propagation, and hydrogen transfer[J]. J Catal, 1994, 145(1): 171-180.
11. [11]
  [11] 龚剑洪, 龙军, 许友好. 催化裂化过程中负氢离子转移反应和氢转移反应的不同特征[J]. 催化学报, 2007, 28(1): 67-72. (GONG Jian-hong, LONG Jun, XU You-hao. Different reaction characteristics of hydride transfer and hydrogen transfer in catalytic cracking[J]. Chin J Catal, 2007, 28(1): 67-72.)
12. [12]
  [12] 朱华元, 张信. 含碱土金属分子筛对 FCC 催化剂催化性能的影响[J]. 石油学报(石油加工), 2001, 17(6): 6-10. (ZHU Hua-yuan, ZHANG Xin. Influence of zeolites containing alkaline earth metal on performance of FCC catalysts[J]. Acta Pet Sin ( Pet Process sect), 2001, 17(6): 6-10.)
13. [13]
  [13] ALERASOOL S, DOOLIN P K, HOFFMAN J F. Matrix acidity determination: A bench scale method for predicting resid cracking of FCC catalysts[J]. Ind Eng Chem Res, 1995, 34(2): 434-439.
14. [14]
  [14] EMEIS C. Determination of integrated molar extinction coefficients for infrared absorption bands of pyridine adsorbed on solid acid catalysts[J]. J Catal, 1993, 141(2): 347-354.
15. [15]
  [15] KORTUNOV P, VASENKOV S, KARGER J. The role of mesopores in intracrystalline transport in USY zeolite: PFG NMR diffusion study on various length scales[J]. J Am Chem Soc, 2005, 127(37): 13055-13059.
16. [16]
  [16] ABBOT J. Role of Brönsted and Lewis acid sites during cracking reactions of alkanes[J]. Appl Catal, 1989, 47(1): 33-44.
17. [17]
  [17] BALLMOOS R V, HAYWARD C T. Matrix vs zeolite contributions to the acidity of fluid cracking catalysts[J]. Stud Surf Sci Catal, 1991, 65: 171-183.
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沈阳化工大学材料科学与工程学院沈阳 110142