Citation: LIU Zhen-zhen, LUO Zhong-yang, MA Shuai, FANG Meng-xiang. Influence of phenolics on hydrodenitrogenation, hydrodesulfurization and hyrodearomatization of coal tar components[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(11): 1327-1333. shu

Influence of phenolics on hydrodenitrogenation, hydrodesulfurization and hyrodearomatization of coal tar components

1.
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

Corresponding author: LUO Zhong-yang,
Received Date: 27 May 2015
Available Online: 14 August 2015
Fund Project: 国家高技术研究发展计划(863计划,2013AA051203) (863计划,2013AA051203)国际合作项目(2011DFR60190,2010DFA72730) (2011DFR60190,2010DFA72730)

The influence of o-cresol on HDN of quinoline, HDS of DBT and HDA of 1-methylnaphthalene were investigated over a commercial catalyst in a fixed bed micro-reactor. The results suggest that o-cresol could strongly inhibit the HDN reaction of quinoline, HDS of DBT and HDA of 1-methylnaphthalene. The inhibition effect increases with the increasing content of o-cresol, which is resulted from the competitive adsorption between o-cresol and quinoline, DBT, and 1-methylnaphthalene. The presence of o-cresol has little effect on product selectivity. The hydrogenation is favored for aromatic ring without side chain, which is accounted for the steric effect.
- coal tar,
- o-cresol,
- HDN,
- HDS,
- HDA
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