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Citation: SHEN Qiu-wan, ZHENG Ying, LUO Cong, ZHENG Chu-guang. Oxygen production performance and structure of SrCo0.8Fe0.2O3-δ synthesized by combined EDTA-citrate complexing process[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(7): 890-896. shu

Oxygen production performance and structure of SrCo0.8Fe0.2O3-δ synthesized by combined EDTA-citrate complexing process

  • 1.

    1. Huazhong University of Science and Technology, State Key Laboratory of Coal Combustion, Wuhan 430074, China;

  • Corresponding author: ZHENG Ying, 
  • Received Date: 27 November 2014
    Available Online: 23 February 2015

    Fund Project: 国家自然科学基金 (51276078) (51276078) 国家重点基础研究发展规划(973计划, 2011CB707301)。 (973计划, 2011CB707301)

  • Perovskite-type metal oxides SrCo0.8Fe0.2O3-δ(SCF182) powder was synthesized by combined EDTA-citrate complexing process. The effects of the pH value of precursor solution on the crystal structure and morphology of synthesized SCF182 powder were investigated by X-ray diffraction and environmental scanning electron microscopy. Fixed-bed experiments were conducted to study the oxygen adsorption/desorption performance of SCF182. The results show that the pH values do not affect the forming of main crystal phase of SCF182 but affect the grain size and microstructure. The net-like porous structure is formed in the system when the pH value of the precursor is 8.The fixed-bed experimental results indicate that the pH value of precursor solution has effects on the oxygen adsorption reaction rate of SCF182. Furthermore, the maximum oxygen desorption amount of SCF182, 42.2 mg/g, can be obtained when the pH value is 8.
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    1. [1]

      [1] 杨伟进, 赵海波, 梅道锋, 郑楚光. Cu 修饰的 Fe2O3/Al2O3 氧载体的循环反应稳定性研究[J]. 燃料化学学报, 2014, 42(1): 121-128. (YANG Wei-jin, ZHAO Hai-bo, MEI Dao-feng, ZHENG Chu-guang.Reactivity and stability of Cu-decorated Fe2O3/Al2O3 oxygen carrier for chemical looping combustion[J].J Fuel Chem Technol, 2014, 42(1): 121-128.)

    2. [2]

      [2] 丁宁, 郑瑛, 罗聪, 吴琪珑, 傅培舫, 郑楚光. 化学链燃烧中 CaSO4 复合载氧体的实验研究[J]. 燃料化学学报, 2011, 39(3): 161-168. (DING Ning, ZHENG Ying, LUO Cong, WU Qi-long, FU Pei-fang, ZHENG Chu-guang. Investigation into compound CaSO4 oxygen carrier for chemical-looping combustion[J]. J Fuel Chem Technol, 2011, 39(3): 161-168.)

    3. [3]

      [3] 罗聪, 郑瑛, 丁宁, 吴琪珑, 郑楚光. 纳米复合钙基高温CO2 吸收剂的合成与性能[J]. 中国电机工程学报, 2011, 31(8): 45-50. (LUO Cong, ZHENG Ying, DING Ning, WU Qi-long, ZHENG Chu-guang. Synthesis and performance of a nano synthetic Ca-based sorbent for high temperature CO2 capture[J]. Proc CSEE, 2011, 31(8): 45-50.)

    4. [4]

      [4] 吴黎明, 潘卫国, 郭瑞堂. 富氧燃烧技术的研究进展与分析[J]. 锅炉技术, 2011, 42(1): 36-39. (WU Li-ming, PAN Wei-guo, GUO Rui-tang. The research and analysis of oxygen combustion technology[J]. Boiler Technol, 2011, 42(1): 36-39.)

    5. [5]

      [5] YANG Q, LIN Y S, BULOW M. High temperature sorption separation of air for producing oxygen-enriched carbon dioxide stream[J]. AIChE J, 2006, 52: 574-581.

    6. [6]

      [6] YANG Q, LIN Y S. Fixed-bed performance for production of oxygen-enriched carbon dioxide stream by perovskite-type ceramic sorbent[J]. Sep Purif Technol, 2006, 49(1): 27-35.

    7. [7]

      [7] YANG Q, LIN Y S. Improved sorbent for high-temperature production of oxygen-enriched carbon dioxide stream[J]. Ind Eng Chem Res, 2007, 46(18): 6025-6031.

    8. [8]

      [8] KUSABA H, SAKAI G, SHIMANOE K, MIURA N. Oxygen-sorptive and desorptive properties of perovskites related oxides under temperature swing condition for oxygen enrichment[J]. Solid State Ionics, 2002, 152-153: 689-694.

    9. [9]

      [9] KUSABA H, SAKAI G, SHIMANOE K, MIURA N, YAMAZOE N. Temperature swing based oxygen enrichment by using perovskites-type oxide[J]. J Mater Sci Lett, 2002, 21(5): 407-409.

    10. [10]

      [10] 张腾, 李振山, 蔡宁生. 利用钙钛矿型金属氧化物制取O2/CO2的实验研究[J]. 工程热物理学报, 2008, 29(9): 1591-1594. (ZHANG Teng, LI Zhen-shan, CAI Ning-sheng. Experimental study of O2-CO2 mixed stream production based on perovskite[J]. J Eng Thermophys, 2008, 29(9): 1591-1594.)

    11. [11]

      [11] 郑瑛, 边关, 罗聪, 吴琪珑, 郑楚光. 钙钛矿型复合载氧体的制备及释氧性能研究[J]. 中国电机工程学报, 2011, 31(35): 90-96. (ZHENG Ying, BIAN Guan, LUO Cong, WU Qi-long, ZHENG Chu-guang. Investigation on the preparation and oxygen desorption ability of different perovskite-type sorbents[J]. Proc CSEE, 2011, 31(35): 90-96.)

    12. [12]

      [12] SHEN Q W, ZHENG Y, LUO C, ZHENG C G. Characteristics of SrCo1<em>-xFexO3-δ perovskite powders with improved O2/CO2 production performance for oxyfuel combustion[J]. Bull Korean Chem Soc, 2014, 35(6): 1613-1616.

    13. [13]

      [13] 沈秋婉, 郑瑛, 马飞艳, 丁宁, 郑楚光. 钙钛矿氧载体SrCo0.8Fe0.2O3-δ制氧性能的实验研究[J]. 工程热物理学报, 2014, 35(1): 192-195. (SHEN Qiu-wan, ZHENG Ying, MA Fei-yan, DING Ning, ZHENG Chu-guang. Experimental study of SrCo0.8Fe0.2O3-δperovskite-type for oxygen production[J]. J Eng Thermophys, 2014, 35(1): 192-195.)

    14. [14]

      [14] 王艳. 钙钛矿型氧化物的制备方法及应用[J]. 天津化工, 2008, 22(3): 39-42. (WANG Yan. The perovskite oxide preparation methods and applications[J]. Tianjin J Chem Eng, 2008, 22(3): 39-42.)

    15. [15]

      [15] 乔梁, 徐天添, 郑精武, 蔡伟, 姜力强. pH值对溶胶凝胶法制备La0.65Sr0.35MnO3的影响[J]. 稀有金属材料与工程, 2010, 39(2): 343-346. (QIAO Liang, XU Tian-tian, ZHENG Jing-wu, CAI Wei, JIANG Li-qiang. Effects of pH value on preparation of La0.65Sr0.35MnO3 by sol-gel process[J]. Rare Metal Mater Eng, 2010, 39(2): 343-346.)

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