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磺化Salen金属配合物插层水滑石选择性催化氧化甘油制备二羟基丙酮的研究

雒京 ,  李洪广 ,  赵宁 ,  王峰 ,  肖福魁

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引用本文: 雒京, 李洪广, 赵宁, 王峰, 肖福魁. 磺化Salen金属配合物插层水滑石选择性催化氧化甘油制备二羟基丙酮的研究[J]. 燃料化学学报, 2015, 43(6): 677-683. shu
Citation:  LUO Jing, LI Hong-guang, ZHAO Ning, WANG Feng, XIAO Fu-kui. Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes[J]. Journal of Fuel Chemistry and Technology, 2015, 43(6): 677-683. shu

磺化Salen金属配合物插层水滑石选择性催化氧化甘油制备二羟基丙酮的研究

    通讯作者: 赵宁,Tel:0351-4049612,E-mail:zhaoning@sxicc.ac.cn;王峰,Tel:0351-4049612,E-mail:wangf@sxicc.ac.cn。; 赵宁,Tel:0351-4049612,E-mail:zhaoning@sxicc.ac.cn;王峰,Tel:0351-4049612,E-mail:wangf@sxicc.ac.cn。
  • 基金项目:

    国家自然科学基金(51206188) (51206188)

    山东省优秀中青年科学家科研奖励基金(BS2013SW032) (BS2013SW032)

    长江学者和创新团队发展计划资助(IRT1294)。 (IRT1294)

摘要: 制备了一系列含不同金属离子的磺化Salen金属配合物插层水滑石催化剂用于甘油催化氧化制备二羟基丙酮(DHA)。利用X射线粉末衍射(XRD)、傅里叶变换红外光谱(FT-IR)及电感耦合等离子发射光谱(ICP)分析手段对催化剂进行了表征。结果表明,磺化Salen配体插入镁铝水滑石(LDH)层板间,金属离子与磺化Salen配体配合,制备出磺化Salen金属配合物插层的水滑石非均相催化剂。反应结果表明,含Cr3+及含Cu2+催化剂有利于H2O2活化,催化活性较高,含Cu2+催化剂利于甘油脱氢,DHA选择性较高。含Cu2+催化剂用于甘油催化氧化反应时,在pH值为7、60 ℃条件下反应4 h,甘油转化率为40.3%,DHA选择性达到52.9%。

English

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  • 收稿日期:  2015-01-26
  • 网络出版日期:  2015-03-10
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