Advanced Search

Citation: ZHOU Guang-lin, WANG Mei-qing, WANG Xiao-sheng, JIANG Wei-li, ZHOU Hong-jun. Removal of COS in coke-oven gas by NiO/ZnO-Al2O3 adsorption[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(4): 470-475. shu

Removal of COS in coke-oven gas by NiO/ZnO-Al2O3 adsorption

  • 1.

    Institute of New Energy, China University of Petroleum(Beijing), Beijing 102249, China

  • Corresponding author: ZHOU Guang-lin, 
  • Received Date: 30 October 2014

    Fund Project: 国家高技术研究发展计划(863计划,2011AA05A202)。 (863计划,2011AA05A202)

  • The NiO/ZnO-Al2O3 adsorbent was prepared by incipient method and characterized by XRD and mercury porosimeter. The performance of the adsorbent in the removal of COS from the simulated coke-oven gas was tested in a fixed-bed reactor. The results show that the appropriate reaction conditions are 350 ℃, 0.40 MPa and GHSV of 500~1 000 h-1. The adsorbent could remove COS from 320~450 mg/m3 to 0.5 mg/m3 as well as olefins from 2.3%~4.5% to 0 without changing other component. The breadthrough sulfer capacity is 17.18%. The regeneration test shows that the crystal form, pore structure and sulfer capacity of the regenerated adsorbent have no significant change compared with the fresh adsorbent. A desulfurization mechanism is proposed as follows:first COS is absorbed on the reduced Ni atoms to form NiS via the breaking of the S-C bond, then NiS is transformed to H2S in the presence of H2, finally H2S is captured by ZnO.
  • 加载中
    1. [1]

      [1] 杨柱荣, 蹇守华, 武振林, 杨彦伟. 焦炉气制甲醇原料气净化工艺浅析[J]. 天然气化工, 2011, 36(6):42-45. (YANG Zhu-rong, JIAN Shou-hua, WU Zhen-lin, YANG Yan-wei. Discussion of feed gas purification technology for production of methanol from coke oven gas[J]. Nat Gas Chem Ind, 2011, 36(6):42-45.)

    2. [2]

      [2] 常宏岗, 王荫砃. 胺法脱硫、硫磺回收工艺现状及发展[J]. 石油与天然气化工, 2002, 3l(21):33-36. (CHANG Hong-gang, WANG Yin-dan. Present situation and development trends on amine desulfurization and sulfur recovery technologies[J]. Chem Eng Oil Gas, 2002, 3l(21):33-36.)

    3. [3]

      [3] 牛刚, 黄玉华, 王经. 低温甲醇洗技术在天然气净化过程中的应用[J]. 天然气化工, 2009, 28(2):26-29. (NIU Gang, HUANG Yu-hua, WANG Jing. Application of the cool methanol absorption technology to the natural gas purification process[J]. Nat Gas Chem Ind, 2009, 28(2):26-29.)

    4. [4]

      [4] 王平尧. 湿式氧化法脱硫技术及焦炉煤气脱硫工艺选择[J]. 化肥设计, 2009, 47(3):22-25. (WANG Ping-yao. Wet oxidation method de-sulfur technology and selection for de-sulfur process of coking-oven gas[J]. Chem Fert Des, 2009, 47(3):22-25.)

    5. [5]

      [5] 王会娜, 上官炬, 王晓鹏, 朱永军. 羰基硫催化水解研究进展[J]. 工业催化, 2007, (2):18-21. (WANG Hui-na, SHANG Guan-ju, WANG Xiao-peng, ZHU Yong-jun. Advances in catalytic hydrolysis of carbonyl sulfide[J]. Ind Catal, 2007, (2):18-21.)

    6. [6]

      [6] WANG H Y, YI H H, NING P, TANG X L, YU L L, HE D, ZHAO S Z. Calcined hydrotalcite-like compounds as catalysts for hydrolysis carbonyl sulfide at low temperature[J]. Chem Eng J, 2011, 166(1):99-104.

    7. [7]

      [7] ANDREY R, VASILE H, DIDIER T, CATHERINE L, DIDIER A, BERNARD C, PHILIPPE T. Methyl mercaptan and carbonyl sulfide traces removal through adsorption and catalysis on zeolites and layered double hydroxides[J]. Appl Catal A:Gen, 2011, 397 (1/2):218-224.

    8. [8]

      [8] 上官炬, 郭汉贤. 氧化铝基COS、CS2水解催化剂表面碱性和催化作用[J]. 分子催化, 1997, (11):337-342. (SHANG Guan-ju, GUO Han-xian. The surface basicity and catalysis over the alumina based catalysts for COS and CS2 hydrolysis[J]. J Mol Catal (China), 1997, (11):337-342.)

    9. [9]

      [9] 柏勇. 铁锰系氧化物脱除合成气中羰基硫的应用基础研究[D]. 上海:华东理工大学, 2011. (BO Yong. Basic application research on iron and manganese oxide for removal of carbonyl sulfide from syngas[D]. Shanghai:East China University of Science and Technology, 2011.)

    10. [10]

      [10] 徐文亚. 羰基硫加氢转化新催化剂的制备与反应性能研究[D]. 辽宁:大连理工大学, 2012. (XU Wen-ya. Preparation and catalytic properties of new catalysts for hydrodesulfurization of carbonyl sulfide[D]. Liaoning:Dalian University of Technology, 2012.)

    11. [11]

      [11] KIDD R T, LENNON D, MEECH S R. Surface plasmon enhanced substrate mediated photochemistry on roughened silver[J]. J Chem Phys, 2000, 113(18):8276-8282.

    12. [12]

      [12] 任晓光, 李子燕, 王学谦, 陈炜, 柏杨巍, 蒋明, 孙百余. 微氧条件下改性活性炭对羰基硫的吸附性能[J]. 化工进展, 2011, (2):425-431. (REN Xiao-guang, LI Zi-yan, WANG Xue-qian, CHEN Wei, BAI Yang-wei, JIANG Ming, SUN Bai-yu. Treatment of COS by modified activated carbon under low-oxygen content conditions[J]. Chem Ind Eng Prog, 2011, (2):425-431.)

    13. [13]

      [13] 伏义路, 李锡青, 徐小云. CO的吸附和歧化反应及其在变换-甲烷化反应中的作用[J]. 燃料化学学报, 1984, 4(12):316-323. (FU Yi-lu, LI Xi-qing, XU Xiao-yun. The role of chemisorption and disproportionation of CO in shift-methanation reaction[J]. J Fuel Chem Technol, 1984, 4(12):316-323.)

  • 加载中
    1. [1]

      Danqing Wu ,  Jiajun Liu ,  Tianyu Li ,  Dazhen Xu ,  Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087

    2. [2]

      Weihan Zhang ,  Menglu Wang ,  Ankang Jia ,  Wei Deng ,  Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043

    3. [3]

      Qianqian Zhong ,  Yucui Hao ,  Guotao Yu ,  Lijuan Zhao ,  Jingfu Wang ,  Jian Liu ,  Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013

    4. [4]

      Fang Niu ,  Rong Li ,  Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102

    5. [5]

      Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe2O3 and NO2 with 2D-COS: The role of SDS, UV and SO2. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038

    6. [6]

      Hongling Yuan ,  Jialin Xie ,  Jiawei Wang ,  Jixiang Zhao ,  Jiayan Liu ,  Qing Feng ,  Wei Qi ,  Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041

    7. [7]

      Xunzhang Fan ,  Yuanjin Zhao ,  Shufang Luo ,  Aihua He . Karl Ziegler: A Pioneer in the Polyolefin Industry – Commemorating the 50th Anniversary of the German Chemist’s Passing. University Chemistry, 2024, 39(8): 389-394. doi: 10.3866/PKU.DXHX202312065

    8. [8]

      Jiaxun Wu ,  Mingde Li ,  Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098

    9. [9]

      Lilong Gao ,  Yuhao Zhai ,  Dongdong Zhang ,  Linjun Huang ,  Kunyan Sui . Exploration of Thiol-Ene Click Polymerization in Polymer Chemistry Experiment Teaching. University Chemistry, 2025, 40(4): 87-93. doi: 10.12461/PKU.DXHX202405143

    10. [10]

      Weina Wang ,  Lixia Feng ,  Fengyi Liu ,  Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022

    11. [11]

      Yan Li ,  Xinze Wang ,  Xue Yao ,  Shouyun Yu . 基于激发态手性铜催化的烯烃E→Z异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053

    12. [12]

      Xiaowu Zhang ,  Pai Liu ,  Qishen Huang ,  Shufeng Pang ,  Zhiming Gao ,  Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021

    13. [13]

      Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403

    14. [14]

      Jingyu Cai ,  Xiaoyu Miao ,  Yulai Zhao ,  Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028

    15. [15]

      Chongjing Liu ,  Yujian Xia ,  Pengjun Zhang ,  Shiqiang Wei ,  Dengfeng Cao ,  Beibei Sheng ,  Yongheng Chu ,  Shuangming Chen ,  Li Song ,  Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036

    16. [16]

      Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260

    17. [17]

      Zunxiang Zeng ,  Yuling Hu ,  Yufei Hu ,  Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO2Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069

    18. [18]

      Feng Zheng ,  Ruxun Yuan ,  Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027

    19. [19]

      Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355

    20. [20]

      Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(594)
  • HTML views(71)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return