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Citation: BI Wen-zhuo, ZHAO Rui-dong, CHEN Tian-ju, WANG Zhi-qi, WU Jin-hu. Effect of binders on the performance of CaSO4 oxygen carrier in chemical looping combustion[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(3): 367-371. shu

Effect of binders on the performance of CaSO4 oxygen carrier in chemical looping combustion

  • 1.

    1. Key Laboratory of Biofuels, Qingdao Institute of Bioenergy & Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China;

  • Corresponding author: ZHAO Rui-dong,  WU Jin-hu, 
  • Received Date: 2 September 2014

    Fund Project: 国家重点基础研究发展规划(973 计划, 2011CB201502) (973 计划, 2011CB201502) 中国博士后科学基金(2014M551978)。 (2014M551978)

  • In order to improve the mechanical strength and reactivity of CaSO4 oxygen carrier, the addition of glycerinum, silica sol and pseudo-boehmitewere to CaSO4 oxygen carriers was applied by mechanical mixing, and the effect on the mechanical strength and the characteristics of reaction was experimentally investigated. The results show that the addition of glycerinum and silica sol significantly improves the mechanical strength of CaSO4 oxygen carrier, while the pseudo-boehmite has little effect. TGA results indicate that the addition of glycerinum and silica sol can accelerate the reaction rate and decrease the reaction time. The XRD analysis demonstrates that the addition of binders doesn't affect the conversion from CaSO4 to CaS and the conversion is nearly complete.
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    1. [1]

      [1] OLAJIRE A A. CO2 capture and separation technologies for end-of-pipe applications-A review[J]. Energy, 2010, 35(6): 2610-2628.

    2. [2]

      [2] ADANEZ J, ABAD A, GARCIA-LABIANO F, GAYAN P, DE DIEGO L F. Progress in chemical-looping combustion and reforming technologies[J]. Prog Energy Combust Sci, 2012, 38(2): 215-282.

    3. [3]

      [3] CAO Y, ZHAO H Y, SIT S P, PAN W P. Lanthanum-promoted copper-based oxygen carriers for chemical looping combustion process[J]. J Therm Anal Calorim, 2014, 116(3): 1257-1266.

    4. [4]

      [4] ANDRUS H E, CHIU J H, THIBEAULT P R, BRAUTSCH A. Alstom’s calcium oxide chemical looping combustion coal power technology development[C]//The 34th International Technical Conference on Clean Coal & Fuel Systems, 2009, Clearwater, Florida, USA.

    5. [5]

      [5] 王保文, 晏蓉, 郑瑛, 赵海波, 郑楚光. CaSO4氧载体煤基合成气化学链燃烧模拟研究[J]. 燃料化学学报, 2011, 39(4): 251-257.(WANG Bao-wen, YAN Rong, ZHENG Ying, ZHAO Hai-bo, ZHENG Chu-guang. Simulated investigation of chemical looping combustion with coal-derived syngas and CaSO4 oxygen carrier[J]. J Fuel Chem Technol, 2011, 39(4): 251-257.)

    6. [6]

      [6] TIAN H J, GUO Q J. Investigation into the behavior of reductive decomposition of calcium sulfate by carbon monoxide in chemical-looping combustion[J]. Ind Eng Chem Res, 2009, 48(12): 5624-5632.

    7. [7]

      [7] 郑敏, 沈来宏, 冯晓琼. CaO 加入条件下煤与 CaSO4氧载体化学链燃烧的反应性能研究[J]. 燃料化学学报, 2014, 42(4): 399-407.(ZHENG Min, SHENG Lai-hong, FENG Xiao-qiong. Study on chemical-looping combustion ofcoal with CaSO4 oxygen carrier assisted by CaO addition[J]. J Fuel Chem Technol, 2014, 42(4): 399-407.)

    8. [8]

      [8] SONG Q L, XIAO R, DENG Z Y, ZHANG H Y, SHENG L H, XIAO J, ZHANG M Y. Chemical-looping combustion of methane with CaSO4 oxygen carrier in a fixed bed reactor[J]. Energy Convers Manage, 2008, 49(11): 3178-3187.

    9. [9]

      [9] SONG Q, XIAO R, DENG Z Y, SHENG L H, ZHANG M Y. Reactivity of a CaSO4 oxygen carrier in chemical-looping combustion of methane in a fixed bed reactor[J]. Korean J Chem Eng, 2009, 26(2): 592-602.

    10. [10]

      [10] 李广涛, 王晓刚, 刘长兵, 徐雪芹. 化学循环燃烧载氧体的研究进展[J]. 化工环保, 2006, 26(5): 395-399.(LI Guang-tao, WANG Xiao-gang, LIU Chang-bing, XU Xue-qin. Research progress in oxygen carrier for chemical looping combustion[J]. Environ Protect Chem Ind, 2006, 26(5): 395-399.)

    11. [11]

      [11] 刘永强, 王志奇, 吴晋沪, 武景丽, 徐梅. 铜基载氧体与可燃固体废弃物化学链燃烧特性研究[J]. 燃料化学学报, 2013, 41(9): 1056-1063.(LIU Yong-qiang, WANG Zhi-qi, WU Jin-hu, WU Jing-li, XU Mei. Investigation on Cu-based oxygen carrier for chemical looping combustion of combustible solid waste[J]. J Fuel Chem Technol, 2013, 41(9): 1056-1063.)

    12. [12]

      [12] LIU S M, LEE D H, LIU M, LI L L, YAN R. Selection and application of binders for CaSO4 oxygen carrier in chemical-looping combustion[J]. Energy Fuel, 2010, 24(12): 6675-6681.

    13. [13]

      [13] JOHANSSON M, MATTISSON T, LYNGFELT A. Comparison of oxygen carriers for chemicallooping combustion[J]. Therm Sci, 2006, 10(3): 93-107.

    14. [14]

      [14] JOHANSSON M, MATTISSON T, LYNGFELT A. Investigation of Mn3O4 with stabilized ZrO2 for chemical looping combustion[J]. Chem Eng Res Des, 2006, 84(9): 807-818.

    15. [15]

      [15] 石司默, 董长青, 覃吴, 王磊, 李文艳, 杨勇平. Fe2O3/粉煤灰载氧体化学链燃烧实验与机理研究[J]. 化工学报, 2013, 63(12): 4010-4018.(SHI Si-mo, DONG Chang-qing, TAN Wu, WANG Lei, LI Wen-yan, YANG Yong-ping. Experimental and theoretical study of Fe2O3/coal ash oxygen carrier in CLC system[J]. J Chem Ind Eng (China), 2013, 63(12): 4010-4018.)

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