Citation: LI Lin, ZHANG Lu-ming, ZHANG Yu-hua, LI Jin-lin. Effect of Ni loadings on the catalytic properties of Ni/MgO(111) catalyst for the reforming of methane with carbon dioxide[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(3): 315-322. shu

Effect of Ni loadings on the catalytic properties of Ni/MgO(111) catalyst for the reforming of methane with carbon dioxide

1.
Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, China

Corresponding author: LI Lin, LI Jin-lin,
Received Date: 5 November 2014

Fund Project: 国家自然科学基金青年基金(21403304)。 (21403304)

The catalytic properties of MgO(111) nanosheet-supported Ni were investigated for the reforming of methane with carbon dioxide with the emphasis on the effect of nickel loadings. The catalytic activity and stability increased with increasing Ni loadings from 2% to 10%, while a further increase in the Ni loading from 10% to 20% led to a negative result. The TEM, XRD, H₂-TPD, TG and Raman characterization results show that the deactivation behavior of Ni/MgO(111) depends on the amount of Ni, while the Ni particle size increased with increasing Ni loadings. The deactivation of the sample with 2% of Ni was probably caused by the Ni oxidation, whereas that of the catalyst with higher content of Ni was due to the deposition of carbonaceous materials.
- carbon dioxide reforming of methane,
- nickel loading amounts,
- MgO(111),
- nickel catalysts,
- deactivation
1. [1]
  [1] FAN M S, ABDULLAH A Z, BHATIA S. Catalytic technology for carbon dioxide reforming of methane to synthesis gas[J]. ChemCatChem, 2009, 1(2): 192-208.
2. [2]
  [2] QIAN L, CAI W, ZHANG L, YE L, LI J, TANG M, YUE B, HE H. The promotion effect of hydrogen spillover on CH₄ reforming with CO₂ over Rh/MCF catalysts[J]. Appl Catal B: Environ, 2015, 164: 168-175.
3. [3]
  [3] 王莉, 敖先权, 王诗瀚. 甲烷与二氧化碳催化重整制取合成气催化剂[J]. 化学进展, 2012, (9): 1696-1706.(WANG Li, AO Xian-quan, WANG Shi-han. Catalysts for carbon dioxide catalytic reforming of methane to synthesis gas[J]. Prog Chem, 2012, (9): 1696-1706.)
4. [4]
  [4] SHANG R, GUO X, MU S, WANG Y, JIN G, KOSSLICK H, SCHULZ A, GUO X Y. Carbon dioxide reforming of methane to synthesis gas over Ni/Si₃N₄ catalysts[J]. Int J Hydrogen Energy, 2011, 36(8): 4900-4907.
5. [5]
  [5] 瑙莫汗, 付晓娟, 雷艳秋, 苏海全. 介孔Ni-β-Mo₂C/SBA-16催化剂在CH₄/CO₂重整制合成气反应中的催化性能[J]. 催化学报, 2013, 34(2): 379-384.(Naomohan, FU Xiao-juan, LEI Yan-qiu, SU Hai-quan. Catalytic performance of mesoporous material supported bimetallic carbide Ni-β-Mo₂C/SBA-16 catalyst for CH₄/CO₂ reforming to syngas[J]. Chin J Catal, 2013, 34(2): 379-384.)
6. [6]
  [6] BRADFORD M C J, VANNICE M A. CO₂ reforming of CH₄[J]. Cat Rev Sci Eng, 1999, 41(1): 1-42.
7. [7]
  [7] WANG N, YU X, WANG Y, CHU W, LIU M. A comparison study on methane dry reforming with carbon dioxide over LaNiO₃ perovskite catalysts supported on mesoporous SBA-15, MCM-41 and silica carrier[J]. Catal Today, 2013, 212(1): 98-107.
8. [8]
  [8] LIU H, LI Y, WU H, TAKAYAMA H, MIYAKE T, HE D. Effects of β-cyclodextrin modification on properties of Ni/SBA-15 and its catalytic performance in carbon dioxide reforming of methane[J]. Catal Commun, 2012, 28(5): 168-173.
9. [9]
  [9] XU W Y, XU N N, LONG W, HU L, HONG S G. Theoretical investigations of the mechanism of CO₂-CH₄ reforming reaction catalyzed by transition metals (Pt, Rh, Ru) under a supercritical condition[J]. Appl Mech Mater, 2013, 291-294: 795-798.
10. [10]
  [10] XU B Q, WEI J M, WANG H Y, SUN K Q, ZHU Q M. Nano-MgO: Novel preparation and application as support of Ni catalyst for CO₂ reforming of methane[J]. Catal Today, 2001, 68(1): 217-225.
11. [11]
  [11] NANDINI A P, KAMAL K P, SUBHASH C D. Deactivation studies over Ni-K/CeO₂-Al₂O₃ catalyst for dry reforming of methane[J]. Ind Eng Chem Res, 2007, 46(6): 1731-1736.
12. [12]
  [12] 郭朋飞, 靳国强, 郭聪秀, 王英勇, 童希立, 郭向云. Yb₂O₃助剂对Ni/SiC催化剂甲烷二氧化碳重整性能的影响[J]. 燃料化学学报, 2014, 42(6): 719-726.(GUO Peng-fei, JIN Guo-qiang, GUO Cong-xiu, WANG Ying-yong, TONG Xi-li, GUO Xiang-yun. Effects of Yb₂O₃ promotor on theperformance of Ni/SiC catalysts in CO₂ reforming of CH₄[J]. J Fuel Chem Technol, 2014, 42(6): 719-726.)
13. [13]
  [13] ANDACHE M, REZAEI M, KAZEMI MOGHADAM M. A nanocrystalline MgO support for Ni catalysts for steam reformingof CH₄[J]. Chin J Catal, 2013, 34(7): 1443-1448.
14. [14]
  [14] 杨雅仙, 秦大伟, 谢辉. MgO改性Ni/γ-Al₂O₃催化剂用于甲烷重整制取合成气研究[J]. 天然气化工, 2012, 37(6): 40-43.(YANG Ya-xian, QIN Da-wei, XIE Hui. Preparation of syngas by methane reforming over magnesium oxide modified nickel/γ-alumina[J]. Nat Gas Chem Ind, 2012, 37(6): 40-43.)
15. [15]
  [15] GADDALLA A M, SOMMER M E. Carbon dioxide reforming of methane on nickel catalysts[J]. Chem Eng Sci, 1989, 44(12): 2825-2829.
16. [16]
  [16] ASHCROFT A, CHEETHAM A, GREEN M. Partial oxidation of methane to synthesis gas using carbon dioxide[J]. Nature, 1991, 352(6332): 225-226.
17. [17]
  [17] KIM G J, CHO D S, KIM K H, KIM J H. The reaction of CO₂ with CH₄ to synthesize H₂ and CO over nickel-loaded Y-zeolites[J]. Catal Lett, 1994, 28(1): 41-52.
18. [18]
  [18] ZHANG L, LI L, LI J, ZHANG Y, HU J. Carbon dioxide reforming of methane over nickel catalyst supported on MgO(111) nanosheets[J]. Top Catal, 2014, 57(6/9): 619-626.
19. [19]
  [19] WANG Y H, LIU H M, XU B Q. Durable Ni/MgO catalysts for CO₂ reforming of methane: Activity and metal-support interaction[J]. J Mol Catal A: Chem, 2009, 299(1): 44-52.
20. [20]
  [20] XIAO H, LIU Z, ZHOU X, ZHU K. A unique method to fabricate Ni_xMg_1-xO (111) nano-platelet solid solution catalyst for CH₄-CO₂ dry reforming[J]. Catal Commun, 2013, 34(5): 11-15.
21. [21]
  [21] ZHU K, HU J, KVBEL C, RICHARDS R. Efficient preparation and catalytic activity of MgO (111) nanosheets[J]. Angew Chem, 2006, 118(43): 7435-7439.
22. [22]
  [22] PARMALIANA A, ARENA F, FRUSTERI F, GIORDANO N F. Temperature-programmed reduction study of NiO-MgO interactions in magnesia-supported Ni catalysts and NiO-MgO physical mixture[J]. J Chem Soc, Faraday Trans, 1990, 86(14): 2663-2669.
23. [23]
  [23] ARENA F, FRUSTERI F, PARMALIANA A, PLYASOVA L, SHMAKOV A N. Effect of calcination on the structure of Ni/MgO catalyst: An X-ray diffraction study[J]. J Chem Soc, Faraday Trans, 1996, 92(3): 469-471.
24. [24]
  [24] KIM J H, SUH D J, PARK T J, KIMA K L. Effect of metal particle size on coking during CO₂ reforming of CH₄ over Ni-alumina aerogel catalysts[J]. Appl Catal A: Gen, 2000, 197(2): 191-200.
25. [25]
  [25] GONZALEZ-DELACRUZ V M, PERENIGUEZ R, TERNERO F, HOLGADO J P, CABALLERO A. In situ XAS study of synergic effects on Ni-Co/ZrO₂ methane reforming catalysts[J]. J Phys Chem C, 2012, 116(4): 2919-2926.
26. [26]
  [26] SOKOLOV S, KONDRATENKO E V, POHL M M, BARKSCHAT A, RODEMERCK U. Stable low-temperature dry reforming of methane over mesoporous La₂O₃-ZrO₂ supported Ni catalyst[J]. Appl Catal B: Environ, 2012, 113-114: 19-30.
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